Benzylsulfonylureas and arylsulfamoylureas

ABSTRACT

Benzylsulfonylureas and arylsulfamoylureas are useful as pre-emergent and post-emergent herbicides and as plant growth regulants.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a division of application Ser. No. 686,796, filed on Dec. 26, 1984, now U.S. Pat. No. 4,609,395, which is a continuation-in-part of application Ser. No. 585,170 filed on Mar. 1, 1984, and now abandoned.

BACKGROUND OF THE INVENTION

European patent application No. 51,466, published May 12, 1982, discloses compounds of the formula ##STR1## where W is a substituted benzyl; Z is CH or N; X is CH₃, OCH₃, or Cl; and Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃, or N(CH₃)₂. The compounds are disclosed to have pre- and post-emergent herbicidal activity and to be useful as plant growth regulators.

European patent application No. 71,441, published Feb. 9, 1983, discloses compounds of the formula ##STR2## where Z is CH or N; X is CH₃ or OCH₃ ; Y is Cl, CH₃, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃, N(CH₃)₂, CH(OCH₃)₂, or ##STR3## and L is ##STR4## where R₁ is H or C₁ -C₃ alkyl; R₂ is H or CH₃, R₅ is H, CH₃, OCH₃, Cl, Br, NO₂, CO₂ R₇, SO₂ R₈, OSO₂ R₉, SO₂ NR₁₀ R₁₁ ; R₆ is H or C₁ -C₃ alkyl; R₆ ' is H or CH₃ ; Q is O, S, or SO₂ ; and Q₁ is CR₃ R₄ or O.

Utility as a pre- or post-emergent herbicide and as a plant growth regulant is disclosed.

European patent application No. 79,683, published May 25, 1983, discloses compounds, useful as herbicides or plant growth regulants, of the formula ##STR5## where Z is CH or N; X and Y are as in European application No. 51,466 (described above) and J is ##STR6## Q is O, S or SO₂ ; R is H or CH₃ ;

R₁ is H, CH₃, OCH₃, Cl, Br, CO₂ R₅, SO₂ R₆, OSO₂ R₇ or SO₂ NR₈ R₉ ;

R₂ and R₃ are independently H or C₁ -C₃ alkyl;

R₄ is H or CH₃ ;

R₅ C₁ -C₃ alkyl, CH₂ CH═CH₂, CH₂ CH₂ OCH₃ or CH₂ CH₂ Cl;

R₆ is C₁ -C₃ alkyl;

R₇ is C₁ -C₃ alkyl or CF₃ ; and

R₈ and R₉ are independently C₁ -C₂ alkyl.

SUMMARY OF THE INVENTION

The present invention relates to novel compounds of Formula I, agriculturally suitable compositions containing them, and their method-of-use as pre-emergent or post-emergent herbicides or plant growth regulants. ##STR7## wherein J is ##STR8## n is 0 or 1; L is CH₂ or O;

Q is CH₂ or O;

Q₁ is O, S or SO₂ ;

Q₂ is O or S;

R is H or CH₃ ;

R₁ is H, F, Cl, Br, CH₃ or OCH₃ ;

R₂ is H or C₁ -C₃ alkyl;

R₃ is H or CH₃ ;

R₄ is H or CH₃ ;

R₅ is H, CH₃ or C₂ H₅ ;

R₆ is H or CH₃ ;

R₇ is H or CH₃ ;

R₈ is F, Cl, Br, OCH₃, SCH₃, SO₂ CH₃, CO₂ CH₃, SO₂ N(CH₃)₂ or OSO₂ CH₃ ;

R₉ is H, OH, C₁ -C₆ alkyl, C₁ -C₆ haloalkyl, C₁ -C₆ alkoxyalkyl, C₃ -C₆ alkenyl, C₃ -C₆ alkynyl, C₁ -C₆ alkoxy, phenyl, C₃ -C₆ cycloalkyl, C₄ -C₇ cycloalkylalkyl, C₁ -C₆ alkylcarbonyl, C₁ -C₆ alkoxycarbonyl, benzyl, C₃ -C₄ haloalkenyl, C₃ -C₆ haloalkynyl, C₃ -C₆ alkylcarbonylalkyl, C₃ -C₆ alkoxycarbonylalkyl or C₁ -C₄ cyanoalkyl;

A is ##STR9## X is CH₃, OCH₃, Cl, Br, OCH₂ CF₃ or OCF₂ H; Y is C₁ -C₃ alkyl, CH₂ F, cyclopropyl, C.tbd.CH, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃, N(CH₃)₂, OCH₂ CH₂ F, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CR(OCH₃)₂, ##STR10## CR(OCH₂ CH₃)₂ or OCF₂ H; Z is CH or N;

X₁ is CH₃, OCH₃, OC₂ H₅ or OCF₂ H;

Y₁ is O or CH₂ ;

X₂ is CH₃, C₂ H₅ or CH₂ CF₃ ;

Y₂ is OCH₃, OC₂ H₅, SCH₃, SC₂ H₅, OCF₂ H, SCF₂ H, CH₃ or CH₂ CH₃ ;

X₃ is CH₃ or OCH₃ ; and

Y₃ is H or CH₃ ;

provided that

(1) when X is Cl or Br, then Z is CH and Y is OCH₃, OC₂ H₅, NHCH₃, N(CH₃)₂ or OCF₂ H; and

(2) when X or Y is OCF₂ H, then Z is CH.

Compounds of formula I that are preferred for reasons of their higher herbicidal activity, greater plant growth regulant activity or more favorable ease of synthesis are:

(1) Compounds in which A is A-1.

(2) Compounds of the scope of (1) where Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅, CH₂ OCH₃, CH₂ F or CF₃ ; and L is CH₂.

(3) Compounds of the scope of (2) where J is J₁, J₃, J₇, J₈, J₁₅ or J₁₆.

(4) Compounds of the scope of (3) where R is H; R₁ is H; and X is CH₃ or OCH₃.

Compounds that are specifically preferred are

1,3-dihydro-N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide;

1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide;

N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-dihydro-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide; and

N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide.

DETAILED DESCRIPTION OF THE INVENTION Synthesis

The compounds of Formula I can be prepared as indicated by one or more of the methods shown below in Equations 1, 2, 3, and 4.

Equation 1 depicts the reaction of sulfonyl isocyanates of Formula II, where J is other than J₁₉, with the appropriate heterocyclic amines, III, to give the desired products of Formula Ia. ##STR11## wherein J, X, Y and Z are as previously defined, R₂ is C₁ -C₃ alkyl and R₉ is other than H or OH.

The reaction of Equation 1 is best carried out in an inert aprotic solvent such as methylene chloride, tetrahydrofuran, or acetonitrile at a temperature between 20° and 80° C. A catalytic amount of 1,4-diazabicyclo[2,2,2]octane (DABCO) may be used to accelerate the reaction. In cases in which the products are insoluble in the reaction solvent, they may be isolated by simple filtration. When the products are soluble, they may be isolated by evaporation of the solvent and trituration of the residue with solvents such as 1-chlorobutane, diethyl ether, or methanol, and filtration.

Compounds of Formula Ib, where J is other than J₃, J₄, J₅, J₆, J₈, J₉, and J₁₂, and where L is --CH₂ --, can be prepared as shown in Equation 2 by treating sulfonamides of Formula IV with the methyl ester of a pyrimidine or triazinecarbamic acid of Formula V in the presence of an equimolar quantity of trimethylaluminum. ##STR12## wherein X, Y and Z are as previously defined and J is as defined above.

The reaction of Equation 2 is best carried out at temperatures between 25° and 83° C. in a solvent such as methylene chloride or 1,2-dichloroethane for 12 to 96 hours under an inert atmosphere, as taught in European Pat. No. 84,244 (issued July 27, 1983). The methyl carbamates, V, can be conveniently synthesized by treatment of the corresponding heterocyclic amines of Formula III with dimethyl carbonate or methyl chloroformate in the presence of a base such as sodium hydride or pyridine.

Alternatively, compounds of Formula Ic, where J is other than J₅, J₆, J₁₀, and J₁₁, and where L is --CH₂ --, can be prepared as shown below in Equation 3 by the reaction of sulfonamides of Formula IV with the phenyl ester of the appropriate carbamic acid, VI, in the presence of an equimolar quantity of a tertiary amine base such as 1,5-diazabicyclo[5.4.0]undec-5-ene (DBU). ##STR13## wherein J, X, Y and Z are as previously defined.

The reaction shown in Equation 3 is carried out at about 23° C. in a suitable solvent such as dioxane or acetonitrile. Aqueous acid work-up affords the desired products as described in European patent application No. 70,804 (published Jan. 26, 1983). The phenyl carbamates, VI, can be synthesized by treating the corresponding heterocyclic amines of Formula III with diphenyl carbonate or phenyl chloroformate in the presence of a base such as sodium hydride or pyridine.

Compounds of Formula Id, where J is other than J₁₅, J₁₇, and J₁₉, and where L is 0, can be prepared as shown below in Equation 4. The intermediate chlorosulfonylurea of Formula VII is formed by treatment of the corresponding heterocyclic amine, III, with commercially available chlorosulfonyl isocyanate and is then allowed to react with an appropriate phenol of Formula VIII. ##STR14## wherein J, X, Y and Z are as previously defined.

The reaction shown in Equation 4 is best carried out according to the methods taught in U.S. Pat. No. 4,391,976.

Sulfonyl isocyanates of Formula IIa, where J is other than J₁₉, and R₂ is C₁ -C₃ alkyl, R₉ is other than hydrogen and hydroxy, and where L is --CH₂ --, can be prepared as shown in Equation 5 by the reaction of the corresponding sulfonamides of general structure IV with phosgene in the presence of n-butyl isocyanate and a catalytic amount of 1,4-diazabicyclo[2.2.2]octane (DABCO). Alternatively, the sulfonyl isocyanates, IIa, may be prepared via phosgenation of the appropriate n-butylureas of Formula IX as represented in Equation 6. ##STR15## wherein J is as previously defined.

The reaction shown in Equation 5 is best carried out according to the procedure described in U.S. Pat. No. 4,238,621. ##STR16## wherein J is as previously defined.

The compounds of Formula IX are conveniently prepared by stirring a mixture of the appropriate sulfonamides, IV, anhydrous potassium carbonate, and n-butyl isocyanate in acetone or methyl ethyl ketone at 25° to 80° C. until all of the isocyanate has reacted. The products are isolated by quenching in dilute mineral acid and recrystallizing the solid product. The compounds IX are treated with phosgene and a catalytic amount of DABCO in refluxing xylene or chlorobenzene in a manner analogous to that described in Equation 5.

Another method for the preparation of sulfonyl isocyanates IIa is shown in Equation 7. Treatment of sulfonamides of Formula IV with thionyl chloride gives intermediate N-sulfinylsulfonamides, X, which afford sulfonyl isocyanates of Formula IIa upon exposure to phosgene in the presence of a catalytic amount of pyridine. ##STR17## wherein J is as previously defined.

The reaction of Equation 7 can best be performed according to the procedure of H. Ulrich, B. Tucker, and A. Sayigh, J. Org. Chem., 34, 3200 (1969).

Sulfonyl isocyanates of Formula IIb, where J is other than J₁₅, J₁₇ or J₁₉, R₂ is C₁ -C₃ alkyl, R₉ is other than hydrogen and hydroxy, and L is 0, can be most easily prepared as shown below in Equation 8 by the reaction of appropriately substituted phenols of Formula VIII with chlorosulfonyl isocyanate. This procedure is taught in U.S. Pat. Nos. 4,191,553 and 4,394,153, and by Lohaus in Chem. Ber., 105, 2791 (1972). ##STR18## wherein J is as previously defined.

The requisite sulfonamides of Formula IVa can be synthesized from the appropriately substituted benzyl chlorides or benzyl bromides, XI, by the three-step sequence of reactions outlined below in Equation 9. ##STR19## wherein X' is chlorine or bromine;

J is J₁, J₂, J₃, J₁₃, J₁₄, J₁₅, J₁₆, J₂₀, or J₂₁ ;

L is --CH₂ --; and

when J is J₁₅ or J₁₆, Q₁ is SO₂.

Equation 9(a)

The conversion of alkyl halides to isothiouronium salts is well precedented in the literature. For relevant examples, see T. B. Johnson and J. M. Sprague, J. Am. Chem. Soc., 58, 1348 (1936); 59, 1837 and 2439 (1937); 61, 176 (1939). In a typical procedure, a benzyl halide of Formula XI is treated with thiourea in a suitable solvent such as ethanol or tetrahydrofuran. Temperatures of 40°-80° C. over onehalf to 4 hours are typically required to complete the reaction. The product salts, XII, are isolated by cooling and filtration or by concentration to remove the solvent. The salts, XII, are generally sufficiently pure to be carried on directly to step (9b) without further purification.

Equation 9(b)

The oxidative chlorination of isothiouronium salts to afford sulfonyl chlorides is most conveniently effected according to the procedure of Johnson as described in J. Am. Chem. Soc., 61, 2548 (1939). Thus, the appropriate isothiouronium salts, XII, are suspended in aqueous acetic acid and treated with at least three equivalents of chlorine at temperatures between 0° and 20° C. The product sulfonyl chlorides of Formula XIII are isolated by filtration or extraction into methylene chloride followed by drying and evaporation of the solvent. No further purification of the sulfonyl chlorides is necessary.

Equation 9(c)

In Equation (9c), the sulfonyl chlorides of Formula XIII are suspended in an aprotic solvent such as diethyl ether, 1-chlorobutane, methylene chloride, or tetrahydrofuran and contacted with an excess of anhydrous ammonia at a temperature of 0° to 25° C. The product sulfonamides of Formula IVa are isolated by filtration and washing with water to remove the byproduct ammonium chloride, and concentrating the organic solution. Frequently, the crude sulfonamides may be used directly to prepare the sulfonyl isocyanates of Formula II. However, they may also be purified first by recrystallization from a suitable organic solvent such as ethanol, acetonitrile or chloroform.

Sulfonamides of Formula IVb can be prepared starting from the appropriate benzyl halides of Formula XI by the three-step sequence of reactions shown below in Equation 10. ##STR20## wherein X' is chlorine or bromine;

J is other than J₂, J₅, J₆, J₁₀ or J₁₁ ; and

L is --CH₂ --.

Equation 10(a)

The displacement reaction of Equation 10(a) is best carried out by treating the benzyl halides XI with sodium sulfite at reflux temperature for 3 to 12 hours in water or aqueous methanol. The solution is cooled and the solvent removed in vacuo to give a residue which is washed with methanol or ethyl acetate and filtered. Evaporation of the filtrate affords the sodium sulfonate salt which is typically carried directly on to the next step. For examples of this reaction, see Reed and Tarter, J. Am. Chem. Soc., 57, 571 (1935); and Latimer and Bost, J. Org. Chem., 5, 24 (1940).

Equation 10(b)

The reaction shown in Equation 10(b) can be effected by warming a mixture of the dried salts of Formula XIV with phosphorous pentachloride or phosphorous oxychloride according to the procedure of S. Hazlet, J. Am. Chem. Soc., 59, 287 (1937) or O. Billeter, Ber. Deut. Chem. Ges., 38, 2018 (1935). The product sulfonyl chlorides, XIII, are isolated either by distillation from the crude reaction mixture or by extraction into a suitable solvent such as methylene chloride or 1-chlorobutane.

Equation 10(c)

The amination reaction of Equation 10(c) is carried out as described above for Equation 9(c).

Benzyl halides of Formulas XIa and XIb (X'=Br or Cl) may be prepared as shown below in Equation 11 by treatment of the appropriately substituted toluene derivatives, XV, with either N-bromosuccinimide (NBS) or N-chlorosuccinimide (NCS). ##STR21## wherein X' is chlorine or bromine;

J is J₇, J₈, J₉, J₁₂, J₁₇, J₁₈, J₁₉, J₂₀ and J₂₁ ;

L is --CH₂ --;

R₁ is H, F, Cl, Br or OCH₃ ; and

when J is J₈ or J₁₂, R₃ is H, and

when J is J₁₇, R₃ and R₄ are H.

The reaction of Equation 11 can be most conveniently carried out by heating a solution of the toluene derivatives, XV, and either N-bromosuccinimide or N-chlorosuccinimide in a suitable solvent such as carbon tetrachloride at reflux temperature. A free radical catalyst such as azoisobutyronitrile or benzoyl peroxide is usually employed to initiate the reaction. When the reaction is complete, the cooled solution is filtered to remove the by-product succinimide and the filtrate concentrated in vacuo. The benzyl halides of Formulas XIa and XIb are often obtained in a sufficiently pure state for further transformation.

An alternate method for the preparation of benzyl chlorides of Formula XIb starting from the appropriate benzyl alcohols of Formula XVI is outlined below in Equation 12. ##STR22## wherein X' is chlorine;

J is other than J₅, J₆, J₁₀ or J₁₁ ; and

L is --CH₂ --.

There exists a wide variety of well known methods for converting alkyl alcohols to the corresponding chlorides. One of the most common procedures involves treatment of the alcohols with thionyl chloride either alone or in the presence of a suitable base such as pyridine. For relevant examples, see the following references: H. Gilman and J. E. Kirby, J. Am. Chem. Soc., 51, 3475 (1929); H. Gilman and A. P. Hewlett, Rec. Trav. Chim., 51, 93 (1932); or M. S. Newman, J. Am. Chem. Soc., 62, 2295 (1940).

The requisite benzyl alcohols of Formula XVI (shown below in Equation 13 for the specific example of J=J₁₆) can be synthesized by reduction of the appropriately substituted benzoic acid derivatives of Formula XVII with diborane in a solvent such as tetrahydrofuran. ##STR23## wherein R₁, R₃, R₄ and Q₁ are as previously defined.

Although the reaction of Equation 13 is shown specifically for J=J₁₆, this reduction is applicable to ring systems J₁, J₂, J₃, J₄, J₁₃, J₁₄, J₁₅, J₁₈, J₁₉, J₂₀ and J₂₁ where L is --CH₂ --. For a description of the use of diborane for reduction of benzoic acid derivatives, see H. C. Brown, J. Org. Chem., 38, 2786 (1973).

Alternatively, benzyl alcohols of Formula XVI (shown below in Equation 14 for the specific example of J=J₁₆) can be synthesized by reduction of the appropriately substituted benzaldehyde derivatives of Formula XVIII with sodium borohydride in a solvent such as ethanol. ##STR24## wherein R₁, R₃, R₄ and Q₁ are as previously defined.

Although the reaction of Equation 14 is shown specifically for J=J₁₆, this reduction is applicable to ring systems J₁, J₂, J₃, J₄, J₇, J₈, J₉, J₁₂, J₁₃, J₁₄, J₁₅, J₁₇, J₁₈, J₁₉, J₂₀ and J₂₁ where L is --CH₂ --. For a description of the use of sodium borohydride for the selective reduction of aldehydes, see S. Chaikin and W. Brown, J. Am. Chem. Soc., 71, 122 (1949).

The aldehydes of Formula XVIII can be prepared by the procedure shown in Equation 15 starting with the appropriate nitriles of Formula XIX (shown for the specific example of J=J₁₆). ##STR25## wherein R₁, R₃, R₄ and Q₁ are as previously defined.

Although the reaction of Equation 15 is shown specifically for J=J₁₆, this transformation is equally applicable to all of the ring systems (L=--CH₂ --) except J₅, J₆, J₁₀, and J₁₁. The reaction shown in Equation 15 can be carried out according to the procedures of H. C. Brown, C. J. Shoaf, and C. P. Garg, Tetrahedron Lett., 9 (1959), and J. A. Marshall, N. H. Andersen, and J. W. Schlicher, J. Org. Chem., 35, 858 (1970).

Benzoic acid derivatives of Formula XVII (shown below in Equation 16 for the specific example of J=J₁₆) can be prepared by hydrolysis of the appropriate nitriles of Formula XIX which are, in turn, prepared by a Sandmeyer reaction on the corresponding aniline derivatives XX. ##STR26## wherein R₁, R₃, R₄ and Q₁ are as previously defined.

As before, while the reactions of Equation 16 are shown specifically for J=J₁₆, these steps are applicable to all ring systems where J is other than J₅, J₆, J₁₀ and J₁₁, and L is --CH₂ --.

Equation 16(a)

The diazotization and cuprous cyanide coupling reaction of Equation 16(a) is best carried out according to the procedure described in Organic Syntheses Coll. Vol. I, p. 514.

Equation 16(b)

Nitriles of Formula XIX are most easily hydrolyzed to the desired carboxylic acids XVII by heating at reflux temperature in concentrated solutions of sulfuric acid or by treatment with 100% phosphoric acid and subsequent exposure to nitrous acid. The products are typically isolated by extraction into aqueous base solution followed by washing with a suitable organic solvent such as ether and acidification of the water layer. For a compilation of references dealing with this process, see R. Wagner and H. Zook, "Synthetic Organic Chemistry," John Wiley & Sons, Inc., New York, 1953, p. 412.

A method similar to that described in Equation 16 above can be applied to the synthesis of phenols of Formula VIII as shown below in Equation 17 (shown for the specific example of J=J₁₆). ##STR27## wherein R₁, R₃, R₄ and Q₁ are as previously defined.

The reaction of Equation 17 is applicable to ring systems J₁, J₂, J₃, J₄, J₅, J₆, J₇, J₈, J₉, J₁₀, J₁₁, J₁₂, J₁₃, J₁₄, J₁₆, J₁₈, J₂₀ and J₂₁ where L is 0. The diazotization and hydrolysis reactions shown in Equation 17 can be carried out according to the following procedures: Stevens and Beutel, J. Am. Chem. Soc., 63, 311 (1941); Grillot and Gormley, J. Am. Chem. Soc., 67, 1968 (1945); and Mosettig and Stuart, J. Am. Chem. Soc., 61, 1 (1939).

The requisite aniline derivatives of Formula XX can be prepared in a straightforward manner by reduction of the corresponding nitro compounds of Formula XXI as shown in Equation 18 (for the example where J=J₁₆). ##STR28## wherein R₁, R₃, R₄, and Q are as previously defined.

Although the reaction of Equation 18 is shown specifically for J=J₁₆, this reduction is applicable to all ring systems J₁ -J₂₁. There exists a wide variety of methods for effecting the reduction of aromatic nitro groups to the corresponding aniline derivatives. One of the more common procedures involves treating the nitro compounds of Formula XXI with a slight excess of stannous chloride dihydrate in concentrated hydrochloric acid solution at temperatures between 25° and 80° C. Alternatively, reduction may be accomplished with iron powder in glacial acetic acid solution as described by Hazlet and Dornfeld, J. Am. Chem. Soc., 66, 1781 (1944), and by West in J. Chem. Soc., 127, 494 (1925). For a general review, see Groggins, "Unit Processes In Organic Synthesis," McGraw-Hill Book Co., New York, 1947, pp. 73-128.

Many of the substituted aromatic nitro compounds of Formula XXI (where it is understood that all ring systems defined in the Summary of Invention are represented) can be synthesized by methods taught in U.S. patent application No. 499,443, filed on May 31, 1983, or by any of several possible synthetic routes known to one skilled in the art.

The intermediate functionalized toluene derivatives of Formula XV (L=--CH₂ --) may also be prepared by straightforward synthetic routes known to one skilled in the art.

The synthesis of heterocyclic amines such as these depicted by Formula III has been reviewed in "The Chemistry of Heterocyclic Compounds," a series published by Interscience Publ., New York and London. Aminopyrimidines are described by D. J. Brown in "The Pyrimidines," Vol. XVI of the series mentioned above. The 2-amino-1,3,5-triazines can be prepared according to the method described by E. M. Smolin and L. Rapaport in "s-Triazines and Derivatives," Vol. XIII.

Agriculturally suitable salts of compounds of Formula I are also useful herbicides and can be prepared in a number of ways known to the art. For example, metal salts can be made by treating compounds of Formula I with a solution of an alkali or alkaline earth metal salt having a sufficiently basic anion (e.g., hydroxide, alkoxide, carbonate or hydride). Quaternary amine salts can be made by similar techniques. Detailed examples of such techniques are given in U.S. Pat. No. 4,127,405.

The compounds of this invention and their preparation are further illustrated by the following examples wherein temperatures are given in degrees centigrade and all parts are by weight unless otherwise designated.

EXAMPLE 1 2,6-Dimethylbenzoic acid, methyl ester

A solution of 10 g of 2,6-dimethylbenzoic acid in 22 g thionyl chloride was stirred at reflux temperature for 2 hours. Removal of the excess thionyl chloride afforded the crude acid chloride as a yellow oil. This intermediate was added to a stirred solution of 4 mL of methanol in 10.8 mL pyridine at 65°-70° C. After completion of the addition, the resulting mixture was stirred at room temperature for 2 hours and then poured into 75 mL ice-water. The aqueous layer was extracted with four 50-mL portions of ether and the combined organic extracts were backwashed with saturated sodium bicarbonate solution, 5% aqueous hydrochloric acid, and water. Drying and evaporation of the solvent gave a pale yellow oil which was purified by bulb-to-bulb distillation (40°-50° C., 0.5 mm Hg) to afford 9.5 g of pure 2,6-dimethylbenzoic acid, methyl ester as a colorless liquid; IR (film) 1725 cm⁻¹ ; NMR(CDCl₃) δ 2.3 (s, 6H), 3.9 (s, 3H), 7.0-7.4 (m, 3H).

EXAMPLE 2 2,6-Bis(α,α'-bromomethyl)benzoic acid, methyl ester

A mixture of 5.0 g of the product from Example 1, 11.1 g of N-bromosuccinimide and 0.1 g of azoisobutyronitrile in 76 mL carbon tetrachloride was heated at reflux temperature for one hour. The solution was cooled to room temperature, filtered, and the filtrate concentrated in vacuo to give a light orange oil. Treatment with ether-hexane (1:1, v/v) afforded 3.0 g of pure 2,6-bis(α,α'-bromomethyl)benzoic acid, methyl ester as a white solid, m.p. 67°-70° C.; IR(nujol) 1720 cm⁻¹ ; NMR(CDCl₃) δ 4.0 (s, 3H), 4.65 (s, 4H), 7.5 (s, 3H).

EXAMPLE 3 7-Bromomethylphthalide

The product from Example 2 (2.0 g) was added to 8 mL of concentrated sulfuric acid and the suspension was warmed to about 60° C. for 3 hours. The solution was allowed to cool and was poured into ice-water. The resulting white precipitate was collected by filtration, washed well with water and dried. Recrystallization from acetone gave 1.0 g of pure 7-bromomethylphthalide as a white powder, m.p. 127.5°-131° C.; IR(KBr) 1755 cm⁻¹ ; NMR(CDCl₃) δ 5.0 (s, 2H), 5.29 (s, 2H), 7.4 (br d, 1H), 7.5 (br d, 1H), 7.6 (dd, 1H).

EXAMPLE 4 7-[[(Amino)(imino)methyl]thiomethyl]phthalide

A solution of 1.0 g of the product from Example 3 in 10 mL tetrahydrofuran was treated with 0.33 g of thiourea and the suspension was warmed to reflux temperature for 15 minutes as a thick, white precipitate formed. The reaction mixture was allowed to cool and was filtered. The collected solid was washed with 1-chlorobutane and dried. The yield of the pure title compound was 1.2 g as a white powder, m.p. 206°-211° C. (dec.); NMR(DMSO-d₆) δ 4.8 (s, 2H), 5.4 (s, 2H), 7.61 (br t, 2H), 7.73 (br t, 1H), 9.1 (brs, 1H), 9.23 (br s, 2H).

EXAMPLE 5 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl chloride

A solution of 9.4 g of the product from Example 4 in 77 mL of 50% aqueous acetic acid was cooled to 0° C. and treated with 8 mL of liquid chlorine. Following the addition, the mixture was stirred at 0°-10° C. for 2 hours, filtered, and the solid was washed well with water. The yield of 1,3-dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl chloride was 5.6 g as an off-white solid, m.p. 103°-105.5° C. (dec); IR(KBr) 1740, 1355, 1200 cm⁻¹.

EXAMPLE 6 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonamide

A solution of 5.6 g of the product from Example 5 in 50 mL tetrahydrofuran was cooled to 0° C. under an atmosphere of nitrogen and was treated with 1.5 mL of anhydrous ammonia. The resulting suspension was stirred at room temperature for 3 hours. The insoluble solids were collected by filtration and were washed with water and dried. The yield of the title compound was 3.8 g as a white powder, m.p. 192°-195° C.; IR(KBr) 3340, 3240, 1740, 1130 cm⁻¹ ; NMR(DMSO-d₆ /CDCl₃) δ 4.9 (s, 2H), 5.4 (s, 2H), 6.7 (br s, 2H) 7.5-7.8 (m, 3H).

EXAMPLE 7 1,3-Dihydro-1-oxo-benzo[c]furan-7-methanesulfonyl isocyanate

A solution of 2.0 g of the product from Example 6 in 25 mL thionyl chloride was heated at reflux temperature for 18 hours. The reaction solution was allowed to cool to room temperature and excess thionyl chloride was removed in vacuo. The resulting residue was treated with 16 g of 10% phosgene in toluene and 5 drops of pyridine. This mixture was stirred at reflux temperature for 3 hours. The solution was allowed to cool, filtered under a stream of nitrogen, and the filtrate was concentrated to give 1,3-dihydro-1-oxobenzo[c]furan-7-methanesulfonyl isocyanate as an orange oil. The infrared spectrum of this compound displayed a characteristic isocyanate stretching absorption at 2240 cm⁻¹ as well as a carbonyl stretching signal at 1750 cm⁻¹.

EXAMPLE 8 1,3-Dihydro-N-[(4,6-dimethoxyprimidine-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide

A solution of 8 mmole of the product from Example 7 in 16 mL dry acetonitrile was treated with 1.2 g of 2-amino-4,6-dimethoxypyrimidine and the mixture was heated to 45°-50° C. under an atmosphere of nitrogen for 2 hours. After being stirred at room temperature for an additional 12 hours, the suspension was filtered and the collected solid was washed well with warm acetonitrile. The yield of the title compound was 1.0 g as a yellow powder, m.p. 181°-184° C. (dec.); IR(KBr) 1765, 1710, 1620, 1355 cm⁻¹ ; NMR(CDCl₃) δ 3.83 (s, 6H), 5.27 (s, 2H), 5.41 (s, 2H), 5.76 (s, 1H), 7.35 (br s, 1H), 7.5 (m, 1H), 7.7 (m, 2H), 12.4 (br s, 1H). ##STR29##

By applying the procedures of Examples 1 through 8, the compounds shown in Tables 1 and 2, following, can be prepared.

                                      TABLE 1                                      __________________________________________________________________________     General Formula 1                                                                                                      m.p.                                   J n L  R.sub.1                                                                             R.sub.9      X     Y        (°C.)                           __________________________________________________________________________     J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            C.sub.2 H.sub.5                                 J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             OC.sub.2 H.sub.5                                J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                              J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     Br    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 F                                      J.sub.1                                                                          0 CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CF.sub.3                                        J.sub.1                                                                          1 CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H     -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    H            CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 CH.sub.2                                                                          H    H            OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    H            CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    H            OCH.sub.3                                                                            Cl                                              J.sub.1                                                                          0 O  H    H            CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 O  H    H            CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 O  H    H            OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H    H            OCH.sub.3                                                                            Cl                                              J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H    CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 O  H    CH.sub.3     CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 O  H    CH.sub.3     Cl    OCH.sub.3                                       J.sub.1                                                                          0 O  H    CH.sub.3     Br    OCH.sub.3                                       J.sub.1                                                                          0 O  H    C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H     -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H    CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          5-F  CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          6-Cl CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          6-Br CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          6-CH.sub.3                                                                          CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          6-OCH.sub.3                                                                         CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                        J.sub.1                                                                          0 O  H    CH.sub.3     OCHF.sub.2                                                                           OCH.sub.3                                       J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            CH(CH.sub.3).sub.2                              J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            cyclopropyl                                     J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            C.tbd.CH                                        J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            NH.sub.2                                        J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            N(CH.sub.3).sub.2                               J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F                            J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            SCH.sub.3                                       J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub.2                       J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 OCH.sub.3                    J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH                              J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2                             J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            C(CH.sub.3)(OCH.sub.3).sub.2                    J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                                            J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            2-methyl-1,3-                                                                  dioxolan-2-yl                                   J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            CH(OC.sub.2 H.sub.5).sub.2                      J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            C(CH.sub.3)(OC.sub.2 H.sub.5).sub.2             J.sub.1                                                                          0 O  H    CH.sub.3     OCH.sub.3                                                                            NHCH.sub.3                                      J.sub.1                                                                          0 O  H    CH.sub.3     Cl    NHCH.sub.3                                      J.sub.1                                                                          0 O  H    --CH.sub.2 CN                                                                               OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H    --(CH.sub.2).sub.3 CN                                                                       CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    OH           CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --(CH.sub.2).sub.3 CH(CH.sub.3).sub.2                                                       Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CF.sub.2 H OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 CH.sub.2 Cl                                                                      Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --(CH.sub.2).sub.5 Cl                                                                       CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 OCH.sub.3                                                                        Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --(CH.sub.2).sub.4 OCH.sub.3                                                                CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 CH═CH.sub.2                                                                  OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 CH═CHCH.sub.3                                                                CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 C.tbd.CH                                                                         OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 C.tbd.C--CH.sub.3                                                                Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --(CH.sub.2).sub.4 C.tbd.CH                                                                 CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --OCH.sub.3  CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --O(CH.sub.2).sub.4 CH.sub.3                                                                Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --C.sub.6 H.sub.5                                                                           CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    cyclopropyl  OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    cyclohexyl   OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    cyclopropylmethyl                                                                           OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    cyclohexylmethyl                                                                            Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --C(O)CH.sub.3                                                                              OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --C(O)(CH.sub.2).sub.5 H                                                                    Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CO.sub.2 C.sub.2 H.sub.5                                                                  Br    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CO.sub.2 (CH.sub.2).sub.4 H                                                               Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 C.sub.6 H.sub.5                                                                  OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 --CH═CH--CH.sub.2 Cl                                                         CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 C.tbd.C--CH.sub.2 Cl                                                             Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH.sub.2 C(O)CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    --CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                      OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    H            CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H    H            CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 CH.sub.2                                                                          H    H            Cl    OCH.sub.3                                       J.sub.1                                                                          0 O  H    H            OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H    H            CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 O  H    H            CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 O  H    H            Cl    OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H     -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 CH.sub.2                                                                          H     -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H     -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 CH.sub.2                                                                          H     -n-C.sub.4 H.sub.9                                                                         Cl    OCH.sub.3                                       J.sub.1                                                                          0 O  H     -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                             CH.sub.3                                        J.sub.1                                                                          0 O  H     -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                             OCH.sub.3                                       J.sub.1                                                                          0 O  H     -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                            OCH.sub.3                                       J.sub.1                                                                          0 O  H     -n-C.sub.4 H.sub.9                                                                         Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.3                                        J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             CH.sub.3                                        J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     Br    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            C.sub.2 H.sub.5                                 J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             OC.sub.2 H.sub.5                                J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                              J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 F                                      J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CF.sub.3                                        J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    H            OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H     -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          7-Cl CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               O  7-Br CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          6-F  CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               O  7-CH.sub.3                                                                          CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               O  7-OCH.sub.3                                                                         CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCHF.sub.2                                                                           OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            cyclopropyl                                     J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            NHCH.sub.3                                      J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            N(CH.sub.3).sub.2                               J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub.2                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2                             J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                                            J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH(OC.sub.2 H.sub. 5).sub.2                     J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     Cl    NHCH.sub.3                                      J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            --C.tbd.CH                                      J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            C(CH.sub.3)(OCH.sub.3).sub.2                    J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    OH           OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    (CH.sub.2).sub.2 CH(CH.sub.3).sub.2                                                         Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 CH.sub.2 Cl                                                                        OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    (CH.sub.2).sub.5 Cl                                                                         CH.sub.3                                                                             OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 OCH.sub.3                                                                          Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    (CH.sub.2).sub.2 OCH.sub.3                                                                  Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 CH═CH.sub.2                                                                    OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 CH═CHCH.sub.2 Cl                                                               CH.sub.3                                                                             OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 CH═CHCH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 C.tbd.CCH.sub.3                                                                    OCH.sub. 3                                                                           OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    OCH.sub.3    Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    O(CH.sub.2).sub.4 CH.sub.3                                                                  Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    C.sub.6 H.sub.5                                                                             OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    cyclopropyl  Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    cyclopentyl  OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    C(O)CH.sub.3 OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CO.sub.2 CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 C.sub.6 H.sub.5                                                                    Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH.sub.2 CH═CHCl                                                                        Cl    OCH.sub.3                                       J.sub.7                                                                          --                                                                               CH.sub.2                                                                          H    CH(CH.sub.3)CO.sub.2 CH.sub.3                                                               Cl    OCH.sub.3                                       __________________________________________________________________________

                                      TABLE 1a                                     __________________________________________________________________________     General Formula 1a                                                                                                                         m.p.               J n  L                                                                               Q  Q.sub.1                                                                           Q.sub.2                                                                          R.sub.1                                                                            R.sub.2                                                                             R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                               X     Y        (°C.)       __________________________________________________________________________     J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Br    OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   H    -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub. 2                                                                         0  CH.sub.2                                                                        -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H    -n-C.sub.3 H.sub.7                                                                 -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H  CH(CH.sub.3).sub.2                                                                   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Br    OCH.sub.3                   J.sub.2                                                                          1  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Br                                                                               CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Cl                                                                               CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               5-F CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               6-CH.sub.3                                                                         CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               6-  CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                                 OCH.sub.3                                                        J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                                                                               181-                                                                           184,d              J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                                                                               180-                                                                           185,d              J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     Cl    OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(CH.sub.3).sub.2          J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    NHCH.sub.3                  J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCF.sub.2 H                 J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCF.sub.2 H                                                                          OCF.sub.2 H                 J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OC.sub.2 H.sub.5).su                                                        b.2                         J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCF.sub.2 H                                                                          OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             1,3-dioxolan-                                                                  2-yl                        J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.2 C.tbd.CH          J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     Br    OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.2 OCH.sub.3          J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     Cl    OCH.sub.3                   J.sub.3                                                                          1  O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          1  O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          1  O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     Cl    OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     Cl    OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     Br    OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     Cl    OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               5-F --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Cl                                                                               --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Br                                                                               --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               5-CH.sub.3                                                                         --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               6-  --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                                 OCH.sub.3                                                        J.sub.3                                                                          1  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.4                                                                          0   CH.sub.2                                                                       -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.4                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.4                                                                          0  O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.4                                                                          1  O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.4                                                                          0  O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.5                                                                          1  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   H    -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.6                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.6                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.6                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.6                                                                          0  --                                                                              -- -- --                                                                               H   H    -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.6                                                                          1  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     Cl    OCH.sub.3                   J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     Br    OCH.sub.3                   J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.8                                                                          -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.8                                                                          -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     Cl    OCH.sub.3                   J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               7-Cl                                                                               --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.9                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.9                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.9                                                                          -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub. 10                                                                        -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     Cl    OCH.sub.3                   J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     Br    OCH.sub.3                   J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     Cl    OCH.sub.3                   J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- CH.sub.2                                                                        O  -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- CH.sub.2                                                                        O  -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.13                                                                         -- O                                                                               O  -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- O                                                                               O  -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.13                                                                         -- O                                                                               CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- O                                                                               CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.14                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.14                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     Br    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  C.sub.2 H.sub.5                                                                   -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     Br    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     Br    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   H  CH.sub.3                                                                          CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                                                                               222-                                                                           222.5              J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.3 208-                                                                           209                J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             CH.sub.3 192-                                                                           193                J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     Br    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     Br    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               6-Cl                                                                               CH.sub.3                                                                            H  H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               6-Cl                                                                               CH.sub.3                                                                            H  H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               6-Cl                                                                               CH.sub.3                                                                            H  H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               6-Cl                                                                               CH.sub.3                                                                            H  H  H  -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     Cl    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     Br    OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               6-Cl                                                                               --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               5-Br                                                                               --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               6-F --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               5-CH.sub.3                                                                         --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               6-  --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                                 OCH.sub.3                                                        J.sub.15                                                                         -- --                                                                              -- S  --                                                                               6-Cl                                                                               --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.16                                                                         -- CH.sub.2                                                                        -- O  --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.16                                                                         -- CH.sub.2                                                                        -- S  --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     Cl    OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- S H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- O H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.18                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- H  H  --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.18                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- CH.sub.3                                                                          H  --     Cl    OCH.sub.3                   J.sub.18                                                                         -- O                                                                               -- -- --                                                                               H   --   H  H  -- H  CH.sub.3                                                                          --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  H  -- -- -- --     Cl    OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          -- -- -- --     Cl    OCH.sub.3                   J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               7-Cl                                                                               --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.21                                                                         -- CH.sub. 2                                                                       -- -- --                                                                               --  --   -- -- -- -- -- F      OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     Cl    OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Br     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SCH.sub.3                                                                             OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- OSO.sub.2 CH.sub.3                                                                    OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     Br    OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- F      OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Br     Cl    OCH.sub.3                   J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SCH.sub.3                                                                             OCH.sub.3                                                                            OCH.sub.3                   J.sub. 21                                                                        -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- OSO.sub.2 CH.sub.3                                                                    OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             CH.sub. 3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     Cl    OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     Br    OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CF.sub.3                    J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.2 CH.sub.2                                                              CH.sub.3                    J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     Cl    NHCH.sub.3                  J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     Cl    OCF.sub.2 H                 J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(CH.sub.3).sub.2          J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    NHCH.sub.3                  J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCF.sub.2 H                 J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH          J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCF.sub.2 H                 J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub. 3                  J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(CH.sub.3).sub.2          J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.8                                                                          --  CH.sub.2                                                                       -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    NHCH.sub.3                  J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH          J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.9                                                                          -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.9                                                                          -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.9                                                                          -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    NHCH.sub.3                  J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub. 3                                                                           -- -- -- -- -- --     Cl    OCH.sub.3                   J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     Cl    NHCH.sub.3                  J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.tbd.CH         J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F        J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                   J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCHF.sub.2                                                                           OCHF.sub.2                  J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  H  -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CHCl       J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  H  -- -- --     Cl    NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub. 2        J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCHF.sub.2                                                                           SCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             CH(OCH.sub.3).sub.2         J.sub.16                                                                         -- CH.sub.2                                                                        -- O  --                                                                               H   --   CH.sub. 3                                                                         H  -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.16                                                                         -- CH.sub.2                                                                        -- S  --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          H  -- -- -- --     Cl    N(CH.sub.3).sub.2           J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             CH(OCH.sub.3).sub.2         J.sub.17                                                                         -- --                                                                              -- -- S H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub. 3                                                                           NHCH.sub.3                  J.sub.18                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- H  H  --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.18                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- CH.sub.3                                                                          H  --     Cl    N(CH.sub.3).sub.2           J.sub.18                                                                         -- O                                                                               -- -- --                                                                               H   --   H  H  -- H  CH.sub.3                                                                          --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F        J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F        J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Br     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- F      OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            C.tbd.CH                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Cl     Cl    NHCH.sub.3                  J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Br     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         --  O                                                                              -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                                                                               148-                                                                           151.5              J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             CH.sub.3 191-                                                                           193.5              J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub. 3                                                                           CH.sub.3                    __________________________________________________________________________

                                      TABLE 2                                      __________________________________________________________________________     General Formula 2                                                                                                       m.p.                                  J n  L  R.sub.1                                                                             R.sub.9      X     Y        (°C.)                          __________________________________________________________________________     J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            C.sub.2 H.sub.5                                J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             OC.sub.2 H.sub.5                               J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                             J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 F                                     J.sub.1                                                                          0  CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CF.sub.3                                       J.sub.1                                                                          1  CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          H    C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          H     -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          H    CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          H    H            OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    H            OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          H    H            CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  O  H    H            CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  O  H    H            CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  O  H    H            OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  O  H    CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  O  H    CH.sub.3     CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  O  H    C.sub.2 H.sub.5                                                                             OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  O  H     -n-C.sub.3 H.sub.7                                                                         OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  O  H    CH(CH.sub.3).sub.2                                                                          OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          1  O  H    CH.sub.3     OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          5-F  CH.sub.3     OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          6-Cl CH.sub.3     OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          6-Br CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          6-CH.sub.3                                                                          CH.sub.3     OCH.sub. 3                                                                           OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          6-OCH.sub.3                                                                         CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                   CH.sub.3                                       J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            CH(CH.sub.3)                                   J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            cyclopropyl                                    J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            C.tbd.CH                                       J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            NH.sub.2                                       J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            N(CH.sub.3).sub.2                              J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F                           J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            SCH.sub.3                                      J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub.2                      J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 OCH.sub.3                   J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH                             J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2                            J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                                           J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            2-methyl-1,3-                                                                  dioxolan-2-yl                                  J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            CH(OC.sub.2 H.sub.5).sub.2                     J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            C(CH.sub.3)(OC.sub.2 H.sub.5).sub.2            J.sub.1                                                                          0  O  H    CH.sub.3     OCH.sub.3                                                                            NHCH.sub.3                                     J.sub.1                                                                          0  O  H    --CH.sub.2 CN                                                                               OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  O  H    --(CH.sub.2).sub.3 CN                                                                       CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    OH           CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --(CH.sub.2).sub.3 CH(CH.sub.3).sub.2                                                       Cl    OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CF.sub.2 H OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 CH.sub.2 Cl                                                                      Cl    OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --(CH.sub.2).sub.5 Cl                                                                       CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 OCH.sub.3                                                                        Cl    OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --(CH.sub.2).sub.4 OCH.sub.3                                                                CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 CH═CH.sub.2                                                                  OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 CH═CHCH.sub.3                                                                CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 C.tbd.CH                                                                         OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --(CH.sub.2).sub.4 C.tbd.CH                                                                 CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --OCH.sub.3  CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --C.sub.6 H.sub.5                                                                           CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    cyclopropyl  OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    cyclohexyl   OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    cyclopropylmethyl                                                                           OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    cyclohexylmethyl                                                                            CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --C(O)CH.sub.3                                                                              OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --C(O)(CH.sub.2).sub.5 H                                                                    OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CO.sub.2 C.sub.2 H.sub.5                                                                  CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CO.sub.2 (CH.sub.2).sub.4 H                                                               CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 C.sub.6 H.sub.5                                                                  OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 --CH═CH--CH.sub.2 Cl                                                         CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 C.tbd.C--CH.sub.2 Cl                                                             CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH.sub.2 C(O)CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    --CH(CH.sub.3)CO.sub.2 C.sub.2 H.sub.5                                                      OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    H            OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H    H            CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  O  H    H            CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  O  H    H            OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  O  H    H            OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H     -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  CH.sub.2                                                                          H     -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                             OCH.sub.3                                      J.sub.1                                                                          0  CH.sub.2                                                                          H     -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                            OCH.sub.3                                      J.sub.1                                                                          0  O  H     -n-C.sub.4 H.sub.9                                                                         CH.sub.3                                                                             CH.sub.3                                       J.sub.1                                                                          0  O  H     -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                            CH.sub.3                                       J.sub.1                                                                          0  O  H     -n-C.sub.4 H.sub.9                                                                         OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H     -n-C.sub.3 H.sub.7                                                                         CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH(CH.sub.3).sub.2                                                                          CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- O  H    CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          7-Cl CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- O  7-Br CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          6-F  CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- O  7-CH.sub.3                                                                          CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- O  7-OCH.sub.3                                                                         CH.sub.3     CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.3                                       J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             CH.sub.3                                       J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            C.sub.2 H.sub.5                                J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     CH.sub.3                                                                             OC.sub.2 H.sub.5                               J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3                             J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH.sub.2 F                                     J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CF.sub.3                                       J.sub.7                                                                          -- CH.sub.2                                                                          H    H            CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    C.sub.2 H.sub.5                                                                             CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            cyclopropyl                                    J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            NHCH.sub.3                                     J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            N(CH.sub.3).sub.2                              J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub.2                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2                            J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                                           J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            CH(OC.sub.2 H.sub.5).sub.2                     J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            --C.tbd.CH                                     J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.3     OCH.sub.3                                                                            C(CH.sub.3)(OCH.sub.3).sub.2                   J.sub.7                                                                          -- CH.sub.2                                                                          H    OH           OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    (CH.sub.2).sub.2 CH(CH.sub.3).sub.2                                                         CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 CH.sub.2 Cl                                                                        OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    (CH.sub.2).sub.5 Cl                                                                         CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 OCH.sub.3                                                                          CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    (CH.sub.2).sub.2 OCH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 CH═CH.sub.2                                                                    OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 CH═CHCH.sub.2 Cl                                                               CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 CH═CHCH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 C.tbd.CCH.sub.3                                                                    OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    OCH.sub.3    OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    O(CH.sub.2).sub.4 CH.sub.3                                                                  CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    C.sub.6 H.sub.5                                                                             OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    cyclopropyl  CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    cyclopentyl  OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    COCH.sub.3   OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CO.sub.2 CH.sub.3                                                                           OCH.sub.3                                                                            OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 C.sub.6 H.sub.5                                                                    CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH.sub.2 CH═CHCl                                                                        CH.sub.3                                                                             OCH.sub.3                                      J.sub.7                                                                          -- CH.sub.2                                                                          H    CH(CH.sub.3)CO.sub.2 CH.sub.3                                                               CH.sub.3                                                                             OCH.sub.3                                      __________________________________________________________________________

                                      TABLE 2a                                     __________________________________________________________________________     General Formula 2a                                                                                                                         m.p.               J n  L                                                                               Q  Q.sub.1                                                                           Q.sub.2                                                                          R.sub.1                                                                            R.sub.2                                                                             R.sub.3                                                                           R.sub.4                                                                           R.sub.5                                                                           R.sub.6                                                                           R.sub.7                                                                           R.sub.8                                                                               X     Y        (°C.)       __________________________________________________________________________     J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   H    -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H    -n-C.sub.3 H.sub.7                                                                 -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H  CH(CH.sub.3).sub.2                                                                   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.2                                                                          1  O                                                                               -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Br                                                                               CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Cl                                                                               CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               5-F CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               6-CH.sub.3                                                                         CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.2                                                                          0  O                                                                               -- -- --                                                                               6-  CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                                 OCH.sub.3                                                        J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                                                                               175-                                                                           183,d              J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.2 OCH.sub.3          J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          0  O                                                                               -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               5-F --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Cl                                                                               --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               6-Br                                                                               --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          0  O                                                                               -- -- --                                                                               5-CH.sub.3                                                                         --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          0  O                                                                               -- -- --                                                                               6-  --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                                  OCH.sub.3                                                        J.sub.3                                                                          1   O                                                                              -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.3                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.3                                                                          1  O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.3                                                                          1  O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.3                                                                          1  O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.4                                                                          1  CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.4                                                                          0  O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.4                                                                          1  O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub. 3                                                                           -- -- -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.5                                                                          1  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   H    -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.6                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.6                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.6                                                                          0  --                                                                              -- -- --                                                                               H   H    -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.6                                                                          1  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub. 3                  J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.3                                                                          -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.8                                                                          -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.8                                                                          -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               7-Cl                                                                               --   H  -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.9                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.9                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub. 9                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   C.sub.2 H.sub.5                                                                     -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.12                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   CH.sub.2                                                                          -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   H  -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   CH.sub.3                                                                          -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.13                                                                         -- CH.sub.2                                                                        O  -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         --  CH.sub.2                                                                       O  -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.13                                                                         -- O                                                                               O  -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- O                                                                               O  -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.13                                                                         -- O                                                                               CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.13                                                                         -- O                                                                               CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.14                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.14                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  C.sub.2 H.sub.5                                                                   -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   H  CH.sub.3                                                                          CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   H  H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                                                                               192-                                                                           194                J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.3 186-                                                                           187                J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub. 3                                                                         H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 OCH.sub.3          J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.2 F                  J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CF.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               6-Cl                                                                               --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               6-Cl                                                                               --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               6-Cl                                                                               --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               5-Br                                                                               --   H  H  CH.sub.3                                                                          -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               6-F --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               5-CH.sub.3                                                                         --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               6-  --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                                 OCH.sub.3                                                        J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               6-Cl                                                                               --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               6-Cl                                                                               --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.16                                                                         -- CH.sub.2                                                                        -- O  --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.16                                                                         -- CH.sub.2                                                                        -- S  --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- S H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          CH.sub.3                                                                          -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- O H   --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.18                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- H  H  --     CH.sub.3                                                                             OCH.sub.3                   J.sub.18                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- CH.sub.3                                                                          H  --     OCH.sub.3                                                                            CH.sub.3                    J.sub.18                                                                         -- O                                                                               -- -- --                                                                               H   --   H  H  -- H  CH.sub.3                                                                          --     CH.sub.3                                                                             OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          -- -- -- --     CH.sub.3                                                                             OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   CH.sub. 3                                                                         CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               7-Cl                                                                               --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.3                   J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH.sub.3                    J.sub. 20                                                                        -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- F      OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Br     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            OCH.sub.3                   J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SCH.sub.3                                                                             OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            OCH.sub.3                                                                               122-                                                                           122.5              J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- OSO.sub.2 CH.sub.3                                                                    OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            CF.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- F      OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Br     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SCH.sub.3                                                                             OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- OSO.sub.2 CH.sub.3                                                                    OCH.sub.3                                                                            CH.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CH.sub.3 187-                                                                           190                J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     CH.sub.3                                                                             OC.sub.2 H.sub.5            J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            CF.sub.3                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- CO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            C.sub.2 H.sub.5             J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(CH.sub.3).sub.2          J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OC.sub.2 H.sub.5).su                                                        b.2                         J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.2                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCF.sub.2 H                                                                          OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             1,3-dioxolan-                                                                  2-yl                        J.sub.3                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.2 C.tbd.CH          J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            CH.sub.2 CH.sub.2                                                              CH.sub.3                    J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.4                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(CH.sub.3).sub.2          J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH          J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.5                                                                          0  --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(CH.sub.3).sub.2          J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.6                                                                          0  CH.sub.2                                                                        -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH          J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.8                                                                          --  CH.sub.2                                                                       -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.8                                                                          -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.9                                                                          -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.9                                                                          -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.9                                                                          -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.10                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.10                                                                         --  --                                                                             -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     CH.sub.3                                                                             CH(OCH.sub.3).sub.2         J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   CH.sub.3                                                                            -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.11                                                                         -- --                                                                              -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             NHCH.sub.3                  J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.12                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            1,3-dioxolan-                                                                  2-yl                        J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.13                                                                         -- CH.sub.2                                                                        CH.sub.2                                                                          -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.tbd.CH         J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F        J.sub.14                                                                         --  CH.sub.2                                                                       -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.2 CF.sub.3                                                                   OCH.sub.3                   J.sub.14                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  H  -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CHCl       J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  H  -- -- --     CH.sub.3                                                                             NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   H  H  CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 C.tbd.CH          J.sub.15                                                                         -- --                                                                              -- O  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          H  -- -- --     OCH.sub.3                                                                            SCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            cyclopropyl                 J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- S  --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          CH.sub.3                                                                          -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.15                                                                         -- --                                                                              -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  H  -- -- --     CH.sub.3                                                                             CH(OCH.sub.3).sub.2         J.sub.16                                                                         -- CH.sub.2                                                                        -- O  --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.16                                                                         -- CH.sub.2                                                                        -- S  --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH═CH.sub                                                        .2                          J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.16                                                                         -- O                                                                               -- SO.sub.2                                                                          --                                                                               H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.17                                                                         -- --                                                                              -- -- O H   --   CH.sub.3                                                                          H  -- -- -- --     CH.sub.3                                                                             CH(OCH.sub.3).sub.2         J.sub.17                                                                         -- --                                                                              -- -- S H   --   CH.sub.3                                                                          H  -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.18                                                                         --  CH.sub.2                                                                       -- -- --                                                                               H   --   H  H  -- H  H  --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.18                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   H  H  -- CH.sub.3                                                                          H  --     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.18                                                                         -- O                                                                               -- -- --                                                                               H   --   H  H  -- H  CH.sub.3                                                                          --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2                                                             OCH.sub.3                   J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  H  -- -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F        J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   CH.sub.3                                                                          CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.19                                                                         -- --                                                                              -- -- --                                                                               H   --   H  CH.sub.3                                                                          -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.20                                                                         -- CH.sub.2                                                                        -- -- --                                                                               H   --   -- -- -- -- -- --     CH.sub.3                                                                             OCH.sub.2 CH.sub.2 F        J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            C.tbd.CH                    J.sub.20                                                                         -- O                                                                               -- -- --                                                                               H   --   -- -- -- -- -- --     OCH.sub.3                                                                            CH(OCH.sub.3).sub.2         J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Br     OCH.sub.3                                                                            N(CH.sub.3).sub.2           J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- F      OCH.sub.3                                                                            NHCH.sub.3                  J.sub. 21                                                                        -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            C.tbd.CH                    J.sub.21                                                                         -- CH.sub.2                                                                        -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            OCH.sub.2 CH.sub.2 F        J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Cl     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- Br     OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- OCH.sub.3                                                                             OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 N(CH.sub.3).sub.2                                                            OCH.sub.3                                                                            NHCH.sub.3                  J.sub.21                                                                         -- O                                                                               -- -- --                                                                               --  --   -- -- -- -- -- SO.sub.2 CH.sub.3                                                                     OCH.sub.3                                                                            NHCH.sub.3                  __________________________________________________________________________

                                      TABLE 3                                      __________________________________________________________________________     General Formula 3                                                                                                                m.p.                         J n L  Q  Q.sub.1                                                                           Q.sub.2                                                                          R.sub.1                                                                          R.sub.2                                                                           R.sub.3                                                                           R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                           R.sub.7                                                                          R.sub.8                                                                               R.sub.9                                                                           X.sub.1                                                                             Y.sub.1                                                                           (°C.)                 __________________________________________________________________________     J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                           O                               J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                            O                               J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                           CH.sub.2                        J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OC.sub.2 H.sub.5                                                                    O                               J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCF.sub.2 H                                                                         O                               J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                           CH.sub.2                        J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                            O                               J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCF.sub.2 H                                                                         O                               J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.2                                                                          0 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCF.sub.2 H                                                                         O                               J.sub.2                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.2                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.2                                                                          1 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCF.sub.2 H                                                                         O                               J.sub.3                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.3                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.3                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                                                                    O                               J.sub.3                                                                          1 O  -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub. 4                                                                         0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.4                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.4                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.5                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.5                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.5                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.6                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.7                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                           CH.sub.2                        J.sub.7                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                            O                               J.sub.8                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.8                                                                          --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.9                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.10                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     OCH.sub.3                                                                         CH.sub.2                             J.sub.10                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.11                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.12                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.12                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.12                                                                         --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.12                                                                         --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.13                                                                         --                                                                               CH.sub.2                                                                          O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.13                                                                         --                                                                               O  O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.13                                                                         --                                                                               CH.sub.2                                                                          CH.sub.2                                                                          -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.14                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.14                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.14                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.15                                                                         --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.15                                                                         --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.15                                                                         --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.15                                                                         --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- O  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- S  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.16                                                                         --                                                                               O  -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.17                                                                         --                                                                               -- -- -- O H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.17                                                                         --                                                                               -- -- -- S H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.18                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               H  H --     -- OCH.sub.3                                                                           O                               J.sub.18                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               CH.sub.3                                                                          H --     -- CH.sub.3                                                                            O                               J.sub.19                                                                         --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.19                                                                         --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.20                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            O                               J.sub.20                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.20                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.20                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                           CH.sub.2                        J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                                                                           CH.sub.2                        J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                           CH.sub.2                        J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                                                                           O                               J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                           O                               __________________________________________________________________________

                                      TABLE 4                                      __________________________________________________________________________     General Formula 4                                                                                                             m.p.                            J n L  Q  Q.sub.1                                                                           Q.sub.2                                                                          R.sub.1                                                                          R.sub.2                                                                           R.sub.3                                                                           R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                           R.sub.7                                                                          R.sub.8                                                                               R.sub.9                                                                           X.sub.1                                                                             (°C.)                    __________________________________________________________________________     J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                             J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                            J.sub.1                                                                          0 CH.sub.                                                                           -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OC.sub.2 H.sub.5                     J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCF.sub.2 H                          J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                             J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                            J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCF.sub.2 H                          J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.2                                                                          0 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.2                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.2                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.2                                                                          1 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.3                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.3                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.3                                                                          1 O  -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.4                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.4                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.4                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.5                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.5                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.5                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.6                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCF.sub.2 H                          J.sub.7                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                            J.sub.7                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                             J.sub.8                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.8                                                                          --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.9                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.10                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.10                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.11                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.12                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.12                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.12                                                                         --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.12                                                                         --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCF.sub.2 H                          J.sub.12                                                                         --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.13                                                                         --                                                                               CH.sub.2                                                                          O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.13                                                                         --                                                                               O  O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.13                                                                         --                                                                               CH.sub.2                                                                          CH.sub.2                                                                          -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.14                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.14                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                             J.sub.14                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                            J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                             J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCHF.sub.2                           J.sub.15                                                                         --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                             J.sub.15                                                                         --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                            J.sub.15                                                                         --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                             J.sub.15                                                                         --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                            J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- O  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- S  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.16                                                                         --                                                                               O  -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.17                                                                         --                                                                               -- -- -- O H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.17                                                                         --                                                                               -- -- -- S H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.18                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               CH.sub.3                                                                          H --     -- CH.sub.3                             J.sub.18                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               H  H --     -- OCH.sub.3                            J.sub.19                                                                         --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.19                                                                         --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.20                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.20                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.20                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                            J.sub.20                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                     J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- OCH.sub.3                            J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                            J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                            J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                            J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                            J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                            J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                            J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- OCH.sub.3                            J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                            J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                            J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                            J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                            J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                            J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                            __________________________________________________________________________

                                      TABLE 5                                      __________________________________________________________________________     General Formula 5                                                                                                               m.p.                          J n L  Q  Q.sub.1                                                                           Q.sub.2                                                                          R.sub.1                                                                          R.sub.2                                                                           R.sub.3                                                                           R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                           R.sub.7                                                                          R.sub.8                                                                               R.sub.9                                                                           X.sub.1                                                                            Y.sub.3                                                                           (°C.)                  __________________________________________________________________________     J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                          CH.sub.3                         J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                          H                                J.sub.1                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                         J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                          CH.sub.3                         J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                          H                                J.sub.1                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                           CH.sub.3                         J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                                                                   H                                J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           CH.sub.3                         J.sub.2                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.2                                                                          0 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.2                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.2                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           CH.sub.3                         J.sub.2                                                                          1 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.3                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           CH.sub.3                         J.sub.3                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.3                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.3                                                                          1 O  -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.4                                                                          0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.4                                                                          0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.4                                                                          1 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub. 5                                                                         0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.5                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OC.sub.2 H.sub.5                                                                   CH.sub.3                         J.sub.6                                                                          0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.7                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                          CH.sub.3                         J.sub.7                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                                                                          H                                J.sub.8                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.8                                                                          --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.9                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.10                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.10                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.11                                                                         --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.12                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.12                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.12                                                                         --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.12                                                                         --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.13                                                                         --                                                                               CH.sub.2                                                                          O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.13                                                                         --                                                                               O  O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.13                                                                         --                                                                               CH.sub.2                                                                          CH.sub.2                                                                          -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.14                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.14                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.14                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           CH.sub.3                         J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.15                                                                         --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.15                                                                         --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.15                                                                         --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.15                                                                         --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.15                                                                         --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- O  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- S  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.16                                                                         --                                                                               CH.sub.2                                                                          -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.16                                                                         --                                                                               O  -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.17                                                                         --                                                                               -- -- -- O H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.17                                                                         --                                                                               -- -- -- S H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                           H                                J.sub.18                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               H  H --     -- OCH.sub.3                                                                          H                                J.sub.18                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               CH.sub.3                                                                          H --     -- OCH.sub.3                                                                          H                                J.sub.19                                                                         --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.19                                                                         --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.20                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.20                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub. 3                                                                         CH.sub.3                         J.sub.20                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          H                                J.sub.20                                                                         --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                                                                          CH.sub.3                         J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- CH.sub.3                                                                           H                                J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                                                                          H                                J.sub.21                                                                         --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                                                                          H                                __________________________________________________________________________

                                      TABLE 6                                      __________________________________________________________________________     General Formula 6                                                                                                                   m.p.                      J  n L  Q  Q.sub.1                                                                           Q.sub.2                                                                          R.sub.1                                                                          R.sub.2                                                                           R.sub.3                                                                           R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                           R.sub.7                                                                          R.sub.8                                                                               R.sub.9                                                                           X.sub.2                                                                             Y.sub.2                                                                             (°C.)              __________________________________________________________________________     J.sub.1                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                            OCH.sub.3                      J.sub.1                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          C.sub.2 H.sub.5                                                                     OC.sub.2 H.sub.5               J.sub.1                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.2 CF.sub.3                                                                   SCH.sub.3                      J.sub.1                                                                           0 CH.sub. 2                                                                         -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.1                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          C.sub.2 H.sub.5                                                                     OCF.sub.2 H                    J.sub.1                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          C.sub.2 H.sub.5                                                                     SCF.sub.2 H                    J.sub.1                                                                           0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          C.sub.2 H.sub.5                                                                     OCH.sub.3                      J.sub.1                                                                           0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.1                                                                           0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          C.sub.2 H.sub.5                                                                     SCF.sub.2 H                    J.sub.2                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.2 CF.sub.3                                                                   SCH.sub.3                      J.sub.2                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.2 CH.sub.3                                                                   SC.sub.2 H.sub.5               J.sub.2                                                                           0 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.2 CH.sub.3                                                                   SC.sub.2 H.sub.5               J.sub.2                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.2 CH.sub.3                                                                   SCH.sub.3                      J.sub.2                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.2 CF.sub.3                                                                   SC.sub.2 H.sub.5               J.sub.2                                                                           1 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.3                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.3                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.3                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.3                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.3                                                                           1 O  -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.4                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.4                                                                           0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.4                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.5                                                                           0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.5                                                                           0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.5                                                                           0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.2 CF.sub.3                                                                   SCH.sub.3                      J.sub.6                                                                           0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.7                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.2 CH.sub.3                                                                   SC.sub.2 H.sub.5               J.sub.7                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.8                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.8                                                                           --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.9                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.10                                                                          --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.10                                                                          --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SC.sub.2 H.sub.5               J.sub.11                                                                          --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.12                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.12                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.12                                                                          --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.12                                                                          --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.13                                                                          --                                                                               CH.sub. 2                                                                         O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.13                                                                          --                                                                               O  O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.13                                                                          --                                                                               CH.sub.2                                                                          CH.sub.2                                                                          -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.14                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.14                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.14                                                                          --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.15                                                                          --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.15                                                                          --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.15                                                                          --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.15                                                                          --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.15                                                                          --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.15                                                                          --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.15                                                                          --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.16                                                                          --                                                                               CH.sub.2                                                                          -- O  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.16                                                                          --                                                                               CH.sub.2                                                                          -- S  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.16                                                                          --                                                                               CH.sub.2                                                                          -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.16                                                                          --                                                                               O  -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.17                                                                          --                                                                               -- -- -- O H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.17                                                                          --                                                                               -- -- -- S H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.18                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               H  H --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.18                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               CH.sub.3                                                                          H --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.19                                                                          --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.19                                                                          --                                                                               -- -- -- --                                                                               H H  -- H --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.20                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.20                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SC.sub.2 H.sub.5               J.sub.20                                                                          --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.20                                                                          --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- C.sub.2 H.sub.5                                                                     SCH.sub.3                      J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- CH.sub.3                                                                            SCH.sub.3                      J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- CH.sub.3                                                                            SCH.sub.3                      __________________________________________________________________________

                                      TABLE 7                                      __________________________________________________________________________     General Formula 7                                                                                                             m.p.                            J  n L  Q  Q.sub.1                                                                           Q.sub.2                                                                          R.sub.1                                                                          R.sub.2                                                                           R.sub.3                                                                           R.sub.4                                                                          R.sub.5                                                                          R.sub.6                                                                           R.sub.7                                                                          R.sub.8                                                                               R.sub.9                                                                           X.sub.3                                                                            (°C.)                    __________________________________________________________________________     J.sub.1                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                           J.sub.1                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                            J.sub.1                                                                           0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                            J.sub.1                                                                           0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                           J.sub.2                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.2                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.2                                                                           0 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.2                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.2                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.2                                                                           1 O  -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.3                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.3                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.3                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.3                                                                           1 O  -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.4                                                                           0 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.4                                                                           0 O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.4                                                                           1 CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.5                                                                           0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.5                                                                           0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.6                                                                           0 -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.7                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          CH.sub.3                            J.sub.7                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     CH.sub.3                                                                          OCH.sub.3                           J.sub.8                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.8                                                                           --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.9                                                                           --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.10                                                                          --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.10                                                                          --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.11                                                                          --                                                                               -- -- -- --                                                                               H CH.sub.3                                                                          -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.12                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.12                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.12                                                                          --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.12                                                                          --                                                                               O  -- -- --                                                                               H -- H  --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.13                                                                          --                                                                               CH.sub.2                                                                          O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.13                                                                          --                                                                               O  O  -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.13                                                                          --                                                                               CH.sub.2                                                                          CH.sub.2                                                                          -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.14                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.14                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.14                                                                          --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.15                                                                          --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                           J.sub.15                                                                          --                                                                               -- -- O  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                            J.sub.15                                                                          --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                            J.sub.15                                                                          --                                                                               -- -- S  --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                           J.sub.15                                                                          --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- CH.sub.3                            J.sub.15                                                                          --                                                                               -- -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H H -- --                                                                               --     -- OCH.sub.3                           J.sub.16                                                                          --                                                                               CH.sub.2                                                                          -- O  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.16                                                                          --                                                                               CH.sub.2                                                                          -- S  --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.16                                                                          --                                                                               CH.sub.2                                                                          -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.16                                                                          --                                                                               O  -- SO.sub.2                                                                          --                                                                               H -- CH.sub.3                                                                          H --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.17                                                                          --                                                                               -- -- -- O H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.17                                                                          --                                                                               -- -- -- S H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.18                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               H  H --     -- OCH.sub.3                           J.sub.18                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- H  H --                                                                               CH.sub.3                                                                          H --     -- CH.sub.3                            J.sub.19                                                                          --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.19                                                                          --                                                                               -- -- -- --                                                                               H -- H  H --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.20                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.20                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.20                                                                          --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- OCH.sub.3                           J.sub.20                                                                          --                                                                               O  -- -- --                                                                               H -- -- --                                                                               --                                                                               -- --                                                                               --     -- CH.sub.3                            J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- OCH.sub.3                           J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                           J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                           J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                           J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                          --                                                                               CH.sub.2                                                                          -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                           J.sub.21                                                                          --                                                                               CH.sub. 2                                                                         -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                           J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Cl     -- OCH.sub.3                           J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               F      -- OCH.sub.3                           J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               Br     -- OCH.sub.3                           J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                           J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               OSO.sub.2 CH.sub.3                                                                    -- OCH.sub.3                           J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               SO.sub.2 N(CH.sub.3).sub.2                                                            -- OCH.sub.3                           J.sub.21                                                                          --                                                                               O  -- -- --                                                                               --                                                                               -- -- --                                                                               --                                                                               -- --                                                                               CO.sub.2 CH.sub.3                                                                     -- OCH.sub.3                           __________________________________________________________________________

Formulations

Useful formulations of the compounds of Formula I can be prepared in conventional ways. They include dusts, granules, pellets, solutions, suspensions, emulsions, wettable powders, emulsifiable concentrates and the like. Many of these may be applied directly. Sprayable formulations can be extended in suitable media and used at spray volumes of from a few liters to several hundred liters per hectare. High strength compositions are primarily used as intermediates for further formulation. The formulation, broadly, contain about 0.1% to 99% by weight of active ingredient(s) and at least one of (a) about 0.1% to 20% surfactant(s) and (b) about 1% to 99.9% solid or liquid inert diluent(s). More specifically, they will contain these ingredients in the following approximate proportions:

                  TABLE 8                                                          ______________________________________                                                     Weight Percent*                                                                Active                                                                         Ingredient                                                                             Diluent(s)                                                                               Surfactant(s)                                    ______________________________________                                         Wettable Powders                                                                             20-90      0-74     1-10                                         Oil Suspensions,                                                                              3-50     40-95     0-15                                         Emulsions, Solutions,                                                          (including Emulsifiable                                                        Concentrates)                                                                  Aqueous Suspension                                                                           10-50     40-84     1-20                                         Dusts          1-25     70-99     0-5                                          Granules and Pellets                                                                         0.1-95     5-99.9   0-15                                         High Strength 90-99      0-10     0-2                                          Compositions                                                                   ______________________________________                                          *Active ingredient plus at least one of a Surfactant or a Diluent equals       100 weight percent.                                                      

Lower or higher levels of active ingredient can, of course, be present depending on the intended use and the physical properties of the compound. Higher ratios of surfactant to active ingredient are sometimes desirable, and are achieved by incorporation into the formulation or by tank mixing.

Typical solid diluents are described in Watkins, et al., "Handbook of Insecticide Dust Diluents and Carriers", 2nd Ed., Dorland Books, Caldwell, New Jersey, but other solids, either mined or manufactured, may be used. The more absorptive diluents are preferred for wettable powders and the denser ones for dusts. Typical liquid diluents and solvents are described in Marsden, "Solvents Guide," 2nd Ed., Interscience, New York, 1950. Solubility under 0.1% is preferred for suspension concentrates; solution concentrates are preferably stable against phase separation at 0° C. "McCutcheon's Detergents and Emulsifiers Annual". MC Publishing Corp., Ridgewood, N.J., as well as Sisely and Wood, "Encyclopedia of Surface Active Agents", Chemical Publishing Co., Inc., New York, 1964, list surfactants and recommended uses. All formulations can contain minor amounts of additives to reduce foaming, caking, corrosion, microbiological growth, etc.

The methods of making such compositions are well known. Solutions are prepared by simply mixing the ingredients. Fine solid compositions are made by blending and, usually, grinding as in a hammer or fluid energy mill. Suspensions are prepared by wet milling (see, for example, Littler, U.S. Pat. No. 3,060,084). Granules and pellets may be made by spraying the active material upon preformed granular carriers or by agglomeration techniques. See J. E. Browning, "Agglomeration", Chemical Engineering, Dec. 4, 1967, pp. 147ff. and "Perry's Chemical Engineer's Handbook", 5th Ed., McGraw-Hill, New York, 1973, pp. 8-57ff.

For further information regarding the art of formulation, see for example:

H. M. Loux, U.S. Pat. No. 3,235,361, Feb. 15, 1966, Col. 6, line 16 through Col. 7, line 19 and Examples 10 through 41;

R. W. Luckenbaugh, U.S. Pat. No. 3,309,192, Mar. 14, 1967, Col. 5, line 43 through Col. 7, line 62 and Examples 8, 12, 15, 39, 41, 52, 53, 58, 132, 138-140, 162-164, 166, 167 and 169-182;

H. Gysin and E. Knusli, U.S. Pat. No. 2,891,855, June 23, 1959, Col. 3, line 66 through Col. 5, line 17 and Examples 1-4;

G. C. Klingman, "Weed Control as a Science", John Wiley and Sons, Inc., New York, 1961, pp. 81-96; and

J. D. Fryer and S. A. Evans, "Weed Control Handbook", 5th Ed., Blackwell Scientific Publications, Oxford, 1968, pp. 101-103.

In the following examples, all parts are by weight unless otherwise indicated.

EXAMPLE 9

    ______________________________________                                         Wettable Powder                                                                ______________________________________                                         N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                                                        80%                                               bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                             amide-1,1-dioxide                                                              sodium alkylnaphthalenesulfonate                                                                            2%                                                sodium ligninsulfonate       2%                                                synthetic amorphous silica   3%                                                kaolinite                    13%                                               ______________________________________                                    

The ingredients are blended, hammer-milled until all the solids are essentially under 50 microns, reblended, and packaged.

EXAMPLE 10

    ______________________________________                                         Wettable Powder                                                                ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                                                        50%                                               dihydro-2-methyl-benzo[B]thiophene-7-methanesulfon-                            amide-1,1-dioxide                                                              sodium alkylnaphthalenesulfonate                                                                            2%                                                low viscosity methyl cellulose                                                                              2%                                                diatomaceous earth           46%                                               ______________________________________                                    

The ingredients are blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in diameter. The product is reblended before packaging.

EXAMPLE 11

    ______________________________________                                         Granule                                                                        ______________________________________                                         Wettable Powder of Example 10                                                                            5%                                                   attapulgite granules      95%                                                  (U.S.S. 20-40 mesh; 0.84-0.42 mm)                                              ______________________________________                                    

A slurry of wettable powder containing 25% solids is sprayed on the surface of attapulgite granules in a double-cone blender. The granules are dried and packaged.

EXAMPLE 12

    ______________________________________                                         Extruded Pellet                                                                ______________________________________                                         1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                                                    25%                                               aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                            amide                                                                          anhydrous sodium sulfate     10%                                               crude calcium ligninsulfonate                                                                               5%                                                sodium alkylnaphthalenesulfonate                                                                            1%                                                calcium/magnesium bentonite  59%                                               ______________________________________                                    

The ingredients are blended, hammer-milled and then moistened with about 12% water. The mixture is extruded as cylinders about 3 mm diameter which are cut to produce pellets about 3 mm long. These may be used directly after drying, or the dried pellets may be crushed to pass a U.S.S. No. 20 sieve (0.84 mm openings). The granules held on a U.S.S. No. 40 sieve (0.42 mm openings) may be packaged for use and the fines recycled.

EXAMPLE 13

    ______________________________________                                         Low Strength Granule                                                           ______________________________________                                         1,3-dihydro-N--[(4,6-dimethoxypyrimidin-2-yl)amino-                                                         0.1%                                              carbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                                 amide                                                                          attapulgite granules        99.9%                                              (U.S.S. 20-40 mesh)                                                            ______________________________________                                    

The active ingredient is dissolved in a solvent and the solution is sprayed upon dedusted granules in a double-cone blender. After spraying of the solution has been completed, the material is warmed to evaporate the solvent. The material is allowed to cool and then packaged.

EXAMPLE 14

    ______________________________________                                         Granule                                                                        ______________________________________                                         1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                                                    80%                                               aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                            amide                                                                          wetting agent                 1%                                               crude ligninsulfonate salt (containing                                                                      10%                                               5-20% of the natural sugars)                                                   attapulgite clay              9%                                               ______________________________________                                    

The ingredients are blended and milled to pass through a 100 mesh screen. This material is then added to a fluid bed granulator, the air flow is adjusted to gently fluidize the material, and a fine spray of water is sprayed onto the fluidized material. The fluidization and spraying are continued until granules of the desired size range are made. The spraying is stopped, but fluidization is continued, optionally with heat, until the water content is reduced to the desired level, generally less than 1%. The material is then discharged, screened to the desired size range, generally 14-100 mesh (1410-149 microns), and packaged for use.

EXAMPLE 15

    ______________________________________                                         Low Strength Granule                                                           ______________________________________                                         1,3-dihydro-N--[(4,6-dimethoxypyrimidin-2-yl)amino-                                                        1%                                                 carbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                                 amide                                                                          N,N--dimethylformamide      9%                                                 attapulgite granules        90%                                                (U.S.S. 20-40 sieve)                                                           ______________________________________                                    

The active ingredient is dissolved in the solvent and the solution is sprayed upon dedusted granules in a double cone blender. After spraying of the solution has been completed, the blender is allowed to run for a short period and then the granules are packaged.

EXAMPLE 16

    ______________________________________                                         Aqueous Suspension                                                             ______________________________________                                         N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                                                       40%                                                bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                             amide-1,1-dioxide                                                              polyacrylic acid thickener  0.3%                                               dodecylphenol polyethylene glycol ether                                                                    0.5%                                               disodium phosphate          1%                                                 monosodium phosphate        0.5%                                               polyvinyl alcohol           1.0%                                               water                       56.7%                                              ______________________________________                                    

The ingredients are blended and ground together in a sand mill to produce particles essentially all under 5 microns in size.

EXAMPLE 17

    ______________________________________                                         Solution                                                                       ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                                                         5%                                               dihydro-2-methyl-benzo[B]thiophene-7-methanesulfon-                            amide-1,1-dioxide, sodium salt                                                 water                        95%                                               ______________________________________                                    

The salt is added directly to the water with stirring to produce the solution, which may then be packaged for use.

EXAMPLE 18

    ______________________________________                                         High Strength Concentrate                                                      ______________________________________                                         1,3-dihydro-N--[(4,6-dimethoxypyrimidin-2-yl)amino-                                                         99%                                               carbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                                 amide                                                                          silica aerogel              0.5%                                               synthetic amorphous silica  0.5%                                               ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce a material essentially all passing a U.S.S. No. 50 screen (0.3 mm opening). The concentrate may be formulated further if necessary.

EXAMPLE 19

    ______________________________________                                         Wettable Powder                                                                ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                                                         90%                                              dihydro-2-methyl-benzo[B]thiophene-7-methanesulfon-                            amide-1,1-dioxide                                                              dioctyl sodium sulfosuccinate                                                                               0.1%                                              synthetic fine silica        9.9%                                              ______________________________________                                    

The ingredients are blended and ground in a hammer-mill to produce particles essentially all below 100 microns. The material is sifted through a U.S.S. No. 50 screen and then packaged.

EXAMPLE 20

    ______________________________________                                         Wettable Powder                                                                ______________________________________                                         1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                                                    40%                                               aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                            amide                                                                          sodium ligninsulfonate       20%                                               montmorillonite clay         40%                                               ______________________________________                                    

The ingredients are thoroughly blended, coarsely hammer-milled and then air-milled to produce particles essentially all below 10 microns in size. The material is reblended and then packaged.

EXAMPLE 21

    ______________________________________                                         Oil Suspension                                                                 ______________________________________                                         N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                                                       35%                                                bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                             amide-1,1-dioxide                                                              blend of polyalcohol carboxylic                                                                             6%                                                esters and oil soluble petroleum                                               sulfonates                                                                     xylene                      59%                                                ______________________________________                                    

The ingredients are combined and ground together in a sand mill to produce particles essentially all below 5 microns. The product can be used directly, extended with oils, or emulsified in water.

EXAMPLE 22

    ______________________________________                                         Dust                                                                           ______________________________________                                         N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocar-                                                       10%                                                bonyl]-2-methyl-benzo[B]thiophene-7-methanesulfon-                             amide-1,1-dioxide                                                              attapulgite                 10%                                                Pyrophyllite                80%                                                ______________________________________                                    

The active ingredient is blended with attapulgite and then passed through a hammer-mill to produce particles substantially all below 200 microns. The ground concentrate is then blended with powdered pyrophyllite until homogeneous.

EXAMPLE 23

    ______________________________________                                         Oil Suspension                                                                 ______________________________________                                         N--[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2,3-                                                        25%                                               dihydro-2-methyl-benzo[B]thiophene-7-methanesul-                               fonamide-1,1-dioxide                                                           polyoxyethylene sorbitol hexaoleate                                                                          5%                                               highly aliphatic hydrocarbon oil                                                                            70%                                               ______________________________________                                    

The ingredients are ground together in a sand mill until the solid particles have been reduced to under about 5 microns. The resulting thick suspension may be applied directly, but preferably after being extended with oils or emulsified in water.

EXAMPLE 24

    ______________________________________                                         Wettable Powder                                                                ______________________________________                                         1,3-dihydro-N--[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-                                                    20%                                               aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfon-                            amide                                                                          sodium alkylnaphthalenesulfonate                                                                            4%                                                sodium ligninsulfonate       4%                                                low viscosity methyl cellulose                                                                              3%                                                attapulgite                  69%                                               ______________________________________                                    

The ingredients are thoroughly blended. After grinding in a hammer-mill to produce particles essentially all below 100 microns, the material is reblended and sifted through a U.S.S. No. 50 sieve (0.3 mm opening) and packaged.

Utility

The compounds of the present invention are active herbicides, having utility for broad-spectrum pre- and/or post-emergence weed control in areas where complete control of all vegetation is desired, such as around fuel storage tanks, ammunition depots, industrial storage areas, parking lots, drive-in theaters, billboards, and highway and railroad structures.

The rates of application for the compounds of the invention are determined by a number of factors, including the types of weeds to be controlled, weather and climate, formulations selected, mode of application, amount of foliage present, etc. In general terms, the subject compounds should be applied at levels of around 0.05 to 5 kg/ha, the lower rates being suggested for use on lighter soils and/or those having a low organic matter content, or for situations where only short-term persistence is required.

The compounds of the invention may be used in combination with any other commercial herbicide; examples of which are those of the triazine, triazole, uracil, urea, amide, diphenylether, carbamate and bipyridylium types. The compounds may also be used in combination with mefluidide.

The herbicidal properties of the subject compounds were discovered in a number of greenhouse tests. The test procedure and results follow.

Test A

Seeds of crabgrass (Digitaria sp.), barnyardgrass (Echinochloa crusgalli), wild oats (Avena fatua), sicklepod (Cassia obtusifolia), morningglory (Ipomoea sp.), cocklebur (Xanthium sp.), sorghum, corn, soybean, cotton rice, sugar beet, rice, wheat and purple nutsedge (Cyperus rotundus) tubers were planted in a growth medium and treated pre-emergence with the test compounds dissolved in a non-phytotoxic solvent. At the same time, these crop and weed species were treated with a soil/foliage application. At the time of treatment, the plants ranged in height from 2 to 18 cm. Treated plants and controls were maintained in a greenhouse for sixteen days, after which all species were compared to controls and visually rated for response to treatment. The ratings, summarized in Table A, are based on a numerical scale extending from 0=no injury, to 10=complete kill. The accompanying descriptive symbols have the following meanings:

C=chlorosis or necrosis;

G=growth retardation; and

H=formative effects.

The test compounds are referenced in the table of results as follows: ##STR30##

                                      TABLE A                                      __________________________________________________________________________             Cmpd.                                                                              Cmpd.                                                                              Cmpd.                                                                              Cmpd.                                                                              Cmpd.                                                          1   2   3   4   5   Cmpd. 6                                                                             Cmpd. 7                                                                             Cmpd. 8                                                                             Cmpd. 9                                                                             Cmpd. 10                                                                            Cmpd.                                                                               Cmpd. 12             Rate kg/ha                                                                             0.05                                                                               0.05                                                                               0.05                                                                               0.05                                                                               0.05                                                                               0.05 0.05 0.05 0.05 0.05 0.05 0.05                 __________________________________________________________________________     POST-EMERGENCE                                                                 Morningglory                                                                           6C,9G                                                                              3C,9G                                                                              3C,6H                                                                              10C 8G  10C  2C,6G                                                                               10C  3C,9G                                                                               3G   9C   10C                  Cocklebur                                                                              5C,8G                                                                              5C,9G                                                                              3C,5G                                                                              10C 5G  3C,9G                                                                               3G   10C  2G   3G   2C   5C,9G                Sicklepod                                                                              4C,8G                                                                              3C,3H                                                                              2C,3G                                                                              9C  3C,3H                                                                              4C,7H                                                                               2C,5G                                                                               9C   2C,3G                                                                               1C   3C,8G                                                                               4C,6G                Nutsedge                                                                               3C,8G                                                                              2G  2C,3G                                                                              5G  2C,3G                                                                              3G   0    3G   5G   0    2C,7G                                                                               2C,6G                Crabgrass                                                                              0   0   2C,5G                                                                              3C,8G                                                                              3C,7G                                                                              3G   0    5G   0    0    2G   2C                   Barnyardgrass                                                                          0   0   3C,6H                                                                              4C,9H                                                                              9C  3C,6H                                                                               3C,8H                                                                               3C,8H                                                                               0    0    0    0                    Wild Oats                                                                              0   0   3C,6G                                                                              3C,8G                                                                              9C  2C,4G                                                                               4C,8G                                                                               2C   0    0    0    0                    Wheat   0   0   3C,8G                                                                              6G  10C 3G   9C   9G   0    0    0    0                    Corn    3C,9H                                                                              1H  3C,9G                                                                              2U,9G                                                                              9C  4C,9H                                                                               4C,9G                                                                               3C,9H                                                                               0    0    1H   3C,8H                Soybean 3C,9G                                                                              2C,8G                                                                              3H  9C  5C,9H                                                                              5C,9G                                                                               3C,8H                                                                               9C   5C,9G                                                                               3C,8G                                                                               5C,9G                                                                               5C,9G                Rice    2C,6G                                                                              2G  5C,9G                                                                              6C,9G                                                                              9C  9C   9C   9C   0    0    0    0                    Sorghum 3C,9H                                                                              2C,9H                                                                              4C,9H                                                                              6C,9H                                                                              9C  5C,9H                                                                               5C,9G                                                                               5C,9H                                                                               0    0    3G   3C,8H                Sugar beet                                                                             9C  4C,9G                                                                              3C,4H                                                                              10C 3C,7H                                                                              9C   3C,7G                                                                               5C,9G                                                                               3C,6G                                                                               0    5C,9G                                                                               5C,9G                Cotton  3C,8H                                                                              3C,5G                                                                              0   9C  3C,7H                                                                              5C,9G                                                                               3C,5G                                                                               5C,9G                                                                               9C   2G   4C,9G                                                                               4C,9G                PRE-EMERGENCE                                                                  Morningglory                                                                           8G  2C,3H                                                                              0   9G  3C,5H                                                                              9G   8G   9G   8G   3G   9G   9G                   Cocklebur                                                                              2C,5H                                                                              2C,2H                                                                              --  8H  0   5H   2H   8H   2H   3G   --   8H                   Sicklepod                                                                              1C,2G                                                                              0   0   2C,7G                                                                              2C  2C,2H                                                                               1C   2C,4G                                                                               5G   4G   2C,7G                                                                               2C                   Nutsedge                                                                               2G  0   0   4G  0   0    2C   3G   3G   0    5G   0                    Crabgrass                                                                              1C  0   2G  2C,5G                                                                              0   0    0    2C,5G                                                                               4G   3G   0    0                    Barnyardgrass                                                                          0   0   1H  4C,9H                                                                              3C,5G                                                                              0    1H   2C,6G                                                                               0    0    3G   3G                   Wild Oats                                                                              0   0   2C,7G                                                                              2C,8H                                                                              8G  2C,3G                                                                               5G   2C,5G                                                                               0    0    3G   5G                   Wheat   4G  3G  2C,8G                                                                              3C,9H                                                                              2C,8H                                                                              2G   2C,9H                                                                               2C,7G                                                                               0    0    4G   8G                   Corn    2C,8H                                                                              0   3C,7H                                                                              2U,9G                                                                              3C,8H                                                                              3C,3G                                                                               2C,8H                                                                               4C,9H                                                                               0    3G   2C,7G                                                                               9G                   Soybean 2C,8H                                                                              0   0   3C,8H                                                                              1C  3C,5H                                                                               2C,2H                                                                               4C,6H                                                                               1H   0    2H   3C,7G                Rice    2C,7G                                                                              2G  3C,8H                                                                              5C,9H                                                                              5C,9H                                                                              7H   5C,9H                                                                               5C,9H                                                                               0    0    2G   2G                   Sorghum 3C,8H                                                                              3C,8H                                                                              3C,9G                                                                              5C,9H                                                                              4C,9H                                                                              3C,7H                                                                               5C,9H                                                                               4C,9G                                                                               0    2G   5G   9G                   Sugar beet                                                                             9C  3C,8G                                                                              0   9C  8G  9C   5G   9C   5G   2G   5C,9G                                                                               5C,9G                Cotton  8H  1C  0   9G  2G  5G   5G   3C,7G                                                                               2G   0    8G   8G                   __________________________________________________________________________

Test B

Postemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled with Woodstown sandy loam soil. One pan was planted with blackgrass (Alpercurus myosuroides), sugar beets, nutsedge (Cyperus rotundus) tubers, crabgrass (Digitaria sanguinalis), sicklepod (Cassia obtusifolia), teaweed (Sida spinosa), jimsonweed (Datura stramonium), velvet leaf (Abutilon theophrasti), oil seed rape (Brassica napus), and giant foxtail (Setaria faberii). The other pan was planted with wheat, cotton, rice, corn, soybean, wild oats (Avena fatua), cocklebur (Xantium pensylvanicum), morninglory (Ipomoea heteracea), johnsongrass (Sorghum halepense) and barnyardgrass (Echinochloa crusgalli). The plants were grown for approximately fourteen days, then sprayed post-emergence with the chemicals dissolved in a non-phytotoxic solvent.

Preemergence

Two round pans (25 cm diameter by 12.5 cm deep) were filled with Woodstown sandly loam soil. One pan was planted with blackgrass, sugar beets, nutsedge, crabgrass, sicklepod, teaweed, jimsonweed, velvetleaf, oil seed rape, and giant foxtail. The other pan was planted with wheat, cotton, rice, corn, soybeans, wild oats, cocklebur, morningglory, johnsongrass, and barnyardgrass. The two pans were sprayed pre-emergence with the chemicals dissolved in a non-phytotoxic solvent.

Treated plants and controls were maintained in the greenhouse for 28 days, then all treated plants were compared to controls and visually rated for plant response utilizing the rating system as described for Test A.

Response ratings are contained in Table B. The data show the potential utility of several of the compounds tested for selective weed control in crops such as wheat, soybeans and cotton.

                                      TABLE B                                      __________________________________________________________________________     PRE-EMERGENCE ON                                                               WOODSTOWN SANDY LOAM                                                                   Compound 1                                                                             Compound 2                                                                             Compound 4.sup.1                                                                              Compound 5                                                                             Compound                                                                              Compound                 __________________________________________________________________________                                                           8                        POST-EMERGENCE                                                                 Rate g/ha                                                                              62 16                                                                               4  62 16 4 62  16  4   1  62 16                                                                               4  62  16 62 16 4                  __________________________________________________________________________     Corn    3G 0 0  0  0  0 100,70                                                                             100,60                                                                             90,30                                                                              80 80 50                                                                               0  70  40 100                                                                               90 60                 Wheat   0  0 0  0  0  0 0,0 0,0 0,0 0,0                                                                               0  0 0  50  0  70 0  0                  Rice    5G 3G                                                                               0  6G 4G 0 80,0                                                                               70,0                                                                               30,0                                                                               0,0                                                                               0  0 0  70  30 90 30 0                  Soybean 9G 6G                                                                               3G 9G 8G 5G                                                                               100,90                                                                             100,90                                                                             100,80                                                                             70,20                                                                             90 80                                                                               60 90  90 100                                                                               90 90                 Cotton  7G 3G                                                                               0  5G 3G 0 100,50                                                                             100,20                                                                             40,0                                                                               0,0                                                                               60 0 0  0   0  90 20 0                  Sugar beet                                                                             7G 3G                                                                               0  9G 5G 0 100,90                                                                             40,90                                                                              0,40                                                                               0,0                                                                               70 60                                                                               30 80  70 70 20 0                  Rape    -- --                                                                               -- -- -- --                                                                               100,100                                                                            100,90                                                                             100,90                                                                             50,40                                                                             100                                                                               90                                                                               60 90  70 100                                                                               90 70                 Crabgrass                                                                              0  0 0  3G 0  0 20,0                                                                               0,0 0,0 0,0                                                                               0  0 0  20  0  60 0  0                  Johnsonqrass                                                                           9G 4G                                                                               0  5G 2G 0 100,90                                                                             100,0                                                                              60,0                                                                               20 0  0 0  20  0  90 90 70                 Blackgrass                                                                             0  0 0  0  0  0 100,70                                                                             70,0                                                                               30,0                                                                               0,0                                                                               80 0 0  70  0  90 80 20                 Barnyardgrass                                                                          3G 0 0  3G 0  0 70,50                                                                              40,0                                                                               0,0 0,0                                                                               0  0 0  0   0  60 20 0                  Nutsedge                                                                               5G 2G                                                                               0  7G 3G 0 40,--                                                                              30,0                                                                               0,0 0,0                                                                               0  0 0  0   0  0  0  0                  Giant Foxtail                                                                          6G 0 0  7G 4G 0 50,0                                                                               0,0 0,0 0,0                                                                               0  0 0  0   0  40 0  0                  Wild Oats                                                                              0  0 0  0  0  0 30,0                                                                               0,0 0,0 0,0                                                                               0  0 0  50  0  40 0  0                  Cocklebur                                                                              8G 3G                                                                               0  9G 5G 2G                                                                               100,90                                                                             60,70                                                                              30,0                                                                               0,0                                                                               100                                                                               90                                                                               70 0   0  80 90 30                 Morningglory                                                                           9G 8G                                                                               3G 9G 6G 3G                                                                               100,90                                                                             40,90                                                                              0,90                                                                               0,50                                                                              100                                                                               90                                                                               80 90  60 100                                                                               100                                                                               90                 Teaweed 0  0 0  4G 0  0 80,80                                                                              50,80                                                                              30,0                                                                               0,0                                                                               50 20                                                                               0  30  0  90 80 20                 Sicklepod                                                                              3G 0 0  6G 3G 0 100,100                                                                            90,90                                                                              30,70                                                                              0,0                                                                               0  0 0  50  0  90 60 20                 Jimsonweed                                                                             8G 6G                                                                               2G 8G 4G 2G                                                                               100,90                                                                             90,90                                                                              60,70                                                                              30,30                                                                             90 80                                                                               0  30  0  80 50 0                  Velvetleaf                                                                             9G 7G                                                                               3G 9G 5G 0 100,100                                                                            100,90                                                                             100,90                                                                             30,50                                                                             80 0 0  70  0  100                                                                               90 40                 __________________________________________________________________________     PRE-EMERGENCE                                                                  Rate g/ha                                                                              250 62  250                                                                               62 16                                                                               250  62    16  250 62  250 62 250                                                                               62 16                 __________________________________________________________________________     Corn    2G  0   0  0  0 90,100                                                                              40,30 0,0 80  0   40  0  50 0  0                  Wheat   0   0   2G 0  0 30,30                                                                               0,0   0,0 0   0   0   0  40 0  0                  Rice    7G  4G  7G 6G 6G                                                                               100  90,100                                                                               40,60                                                                              80  30  90  70 100                                                                               90 50                 Soybean 3G  0   2C 0  0 80,100                                                                              60,50 20,0                                                                               70  20  40  0  70 0  0                  Cotton  7G  2G  0  0  0 40,60                                                                               0,50  0,0 20  0   20  0  30 0  0                  Sugar beet                                                                             9G  3G  10G                                                                               8G 0 90,100                                                                              30,100                                                                               0,50                                                                               80  20  80  30 60 0  0                  Rape    --  --  -- -- --                                                                               100  80,50 30,0                                                                               90  30  60  20 90 20 0                  Crabgrass                                                                              9G  5G  9G 8G 6G                                                                               90,60                                                                               0,30  0,0 0   0   20  0  60 30 0                  Johnsongrass                                                                           8G  4G  8G 5G 0 90,100                                                                              90,90 80,60                                                                              90  80  70  30 90 90 30                 Blackgrass                                                                             8G  3G  8G 4G 0 90,100                                                                              70,80 0,40                                                                               90  80  90  60 90 80 30                 Barnyardgrass                                                                          4G  2G  3G 0  0 90,100                                                                              70,60 20,20                                                                              70  0   0   0  90 50 0                  Nutsedge                                                                               8G  5G  8G 5G 2G                                                                               0,0  0,0   0,0 70  20  30  0  20 0  0                  Giant Foxtail                                                                          6G  2G  4G 2G 0 100  70,70 0,0 70  0   20  0  90 50 0                  Wild Oats                                                                              0   0   0  0  0 60,40                                                                               30,0  0,0 0   0   0   0  80 20 0                  Cocklebur                                                                              8G  0   3G 0  0 80,90                                                                               70,60 0,40                                                                               90  0   0   0  60 0  0                  Morningglory                                                                           0   0   3G 0  0 90,80                                                                               20,30 0,0 90  0   0   0  0  0  0                  Teaweed 9G  5G  9G 5G 0 90,90                                                                               50,50 0,0 60  20  60  0  90 50 20                 Sicklepod                                                                              10G 6G  8G 8G 5G                                                                               70,50                                                                               30,20 0,0 0   0   50  0  70 20 0                  Jimsonweed                                                                             8G  6G  9G 6G 0 90,100                                                                              70,90 20,30                                                                              90  50  50  30 90 40 0                  Velvetleaf                                                                             8G  4G  8G 3G 0 90,100                                                                              70,60 20,30                                                                              50  0   50  30 80 30 0                  __________________________________________________________________________      Note: there are two sets of data for each rate tested.     PG,103         

What is claimed is:
 1. A compound of the formula ##STR31## and agriculturally suitable salts thereof, wherein J is ##STR32## n is 0 or 1; L is CH₂ or O;Q is CH₂ or O; Q₁ is O, S or SO₂ ; Q₂ is O or S; R is H or CH₃ ; R₁ is H, F, Cl, Br, CH₃ or OCH₃ ; R₂ is H or C₁ -C₃ alkyl; R₃ is H or CH₃ ; R₄ is H or CH₃ ; R₅ is H, CH₃ or C₂ H₅ ; R₆ is H or CH₃ ; R₇ is H or CH₃ ; R₈ is F, Cl, Br, OCH₃, SCH₃, SO₂ CH₃, CO₂ CH₃, SO₂ N(CH₃)₂ or OSO₂ CH₃ ; R₉ is H, OH, C₁ -C₆ alkyl, C₁ -C₆ haloalkyl, C₁ -C₆ alkoxyalkyl, C₃ -C₆ alkenyl, C₃ -C₆ alkynyl, C₁ -C₆ alkoxy, phenyl C₃ -C₆ cycloalkyl, C₄ -C₇ cycloalkylalkyl, C₁ -C₆ alkylcarbonyl, C₁ -C₆ alkoxycarbonyl, benzyl, C₃ -C₄ haloalkenyl, C₃ -C₆ haloalkynyl, C₃ -C₆ alkylcarbonylalkyl, C₃ -C₆ alkoxycarbonylalkyl or C₁ -C₄ cyanoalkyl; A is ##STR33## X is CH₃, OCH₃, OCH₂ CF₃ or OCF₂ H; Y is C₁ -C₃ alkyl, CH₂ F, cyclopropyl, C.tbd.CH, OCH₃, OC₂ H₅, CH₂ OCH₃, NH₂, NHCH₃, N(CH₃)₂, OCH₂ CH₂ F, CF₃, SCH₃, OCH₂ CH═CH₂, OCH₂ C.tbd.CH, OCH₂ CH₂ OCH₃, CR(OCH₃)₂, ##STR34## CR(OCH₂ CH₃)₂ or OCF₂ H; and Z is N; provided that X and Y are other than OCF₂ H.
 2. A compound of claim 1 where A is A-1.
 3. A compound of claim 2 where Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅, CH₂ OCH₃, CH₂ F or CF₃ ; and L is CH₂.
 4. A compound of claim 3 where J is J₁, J₃, J₇, J₈, J₁₅ or J₁₆.
 5. A compound of claim 4 where R is H; R₁ is H; and X is CH₃ or OCH₃.
 6. A compound of claim 2 where R is H; R₉ is H or C₁ -C₃ alkyl; X is CH₃ or OCH₃ ; Y is CH₃, C₂ H₅, OCH₃, OC₂ H₅, CH₂ OCH₃, CH₂ F, or CF₃.
 7. The compound of claim 1 which is 1,3-dihydro-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-1-oxo-benzo[c]furan-7-methanesulfonamide.
 8. The compound of claim 1 which is N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)aminocarbonyl]-2-methyl-benzo[B]thiophene-7-methanesulfonamide-1,1-dioxide.
 9. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 1 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 10. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 3 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 11. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 4 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 12. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 5 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 13. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 6 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 14. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 7 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 15. A composition for the control of undesirable vegetation consisting essentially of a compound of claim 8 and at least one of (a) a surface active agent, and (b) a solid or liquid diluent.
 16. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 1. 17. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 3. 18. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 4. 19. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 5. 20. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 6. 21. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 7. 22. A method for the control of undesirable vegetation comprising applying to the locus of such vegetation an herbicidally effective amount of a compound of claim
 8. 